Tc(NBCl2Ph)Cl-2(Me2PhP)(3)] and [Tc(NBH3)Cl-2(Me2PhP)(3)] - the first technetium complexes with nitrido bridges between technetium and boron [German

Hagenbach A.; Abram U.

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Tc(NBCl2Ph)Cl-2(Me2PhP)(3)] and [Tc(NBH3)Cl-2(Me2PhP)(3)] - the first technetium complexes with nitrido bridges between technetium and boron [German

机译：Tc（NBCl2Ph）Cl-2（Me2PhP）（3）]和[Tc（NBH3）Cl-2（Me2PhP）（3）]-第一种在tech和硼之间具有亚硝基桥的tech络合物[德国]

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TcNCl2(Me2PhP)(3)] reacts with BCl2Ph or BH3 THF at low temperatures under formation of complexes containing a nitrido bridge between technetium and boron. The compounds are instable and decompose at room temperature under cleavage of the N-B bonds. The pale-purple [Tc(NBCl2Ph)Cl-2(Me2PhP)(3)] crystallizes in the orthorhombic space group Fdd2. The Tc=N bond is only slightly lengthened by the formation of the N-B bond of 1.564(4) Angstrom. However, a considerable lengthening of the Tc-Cl bond in trans position to the nitrido ligand is observed which can be attributed to an decreasing of the structural trans influence of the nitrido moiety. A similar structural feature can be found in [Tc(NBH3)Cl-2(Me2PhP)(3)] which is the first structurally characterized transition metal complex containing a nitrido bridge to unsubstituted borane. [References: 17

机译：TcNCl2（Me2PhP）（3）]在低温下与BCl2Ph或BH3 THF反应，形成含tech与硼之间的亚硝基桥的配合物。该化合物是不稳定的，并且在室温下由于N-B键的断裂而分解。浅紫色[Tc（NBCl2Ph）Cl-2（Me2PhP）（3）]在正交晶体空间群Fdd2中结晶。通过形成1.564（4）埃的N-B键，仅略微延长了Tc = N键。然而，观察到Tc-Cl键在亚硝基配体的反式位置上的相当大的延长，这可归因于氮离子部分的结构反式影响的降低。在[Tc（NBH3）Cl-2（Me2PhP）（3）]中可以找到类似的结构特征，它是第一个在结构上具有特征的过渡金属配合物，其中包含与未取代的硼烷的亚硝基桥。 [参考：17

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2002年第1期|共3页
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Hagenbach A.; Abram U.;
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1. Tc(NBCl2Ph)Cl-2(Me2PhP)(3)] and [Tc(NBH3)Cl-2(Me2PhP)(3)] - the first technetium complexes with nitrido bridges between technetium and boron [German [J] . Hagenbach A., Abram U. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第1期

机译：Tc（NBCl2Ph）Cl-2（Me2PhP）（3）]和[Tc（NBH3）Cl-2（Me2PhP）（3）]-第一种在tech和硼之间具有亚硝基桥的tech络合物[德国]
2. {ReN(Me2PhP)(Et(2)dtc)Cl}(2){ReN(Et(2)dtc)(2)}(2){SbCl3}(2)] - A novel tetranuclear rhenium complex with asymmetric nitrido bridges [German [J] . Stelzer JB., Hagenbach A., Abram U. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第3期

机译：{ReN（Me2PhP）（Et（2）dtc）Cl}（2）{ReN（Et（2）dtc）（2）}（2）{SbCl3}（2）]-带有不对称氮桥的新型四核rh配合物[德语
3. Synthesis and crystal structures of the complexes [(Me2PhP)(3)Cl2Re equivalent to N-IrCl2(C5Me5)], [(Me2PhP)(3)Cl2Re equivalent to N-IrCl(COD)], [PPh4][O3Os equivalent to N-IrCl2(C5Me5)], and [PPh4][O3Os equivalent to N-IrCl(COD)] with nitrido bridge [J] . Schwarz S., Niquet E., Saez AS., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第14期

机译：[[Me2PhP]（3）Cl2Re相当于N-IrCl2（C5Me5）]，[[Me2PhP]（3）Cl2Re相当于N-IrCl（COD）]，[PPh4] [O3Os相当于N-IrCl2（C5Me5）]和带有亚硝基桥的[PPh4] [相当于N-IrCl（COD）的O3Os]
4. NOVEL TECHNETIUM CHEMISTRY AND RADIOPHARMACEUTICALS: Tc(V), Tc(III) or Tc(I)- WHICH WAY TO GO FOR KEEPING Tc RADIOPHARMACEUTICALS ALIVE? [C] . R. ALBERTO, S. KUNZE, S. MUNDWILER, Trends in Radiopharmaceuticals(ISTR-2005) . 2007

机译：新型化学和放射性药物：Tc（V），Tc（III）或Tc（I）-哪些方法可以保留Tc放射性药物？
5. Ruthenium complexes with imidazole ligands and the oxidation of an oxo-bridged technetium complex. [D] . Hiller, Cecil Duane. 1995

机译：带有咪唑配体的钌配合物和羰基tech配合物的氧化。
6. The synthesis and structural characterization of the technetium nitrosyl complexes TcCl(NO)(SC5H4N)(PPh3)2 and Tc(NO)(SC5H4N)2(PPh3) [O] . Terrence L. Nicholson, Ashfaq Mahmood, Peter Muller, -1

机译：亚硝基复合物的合成和结构表征TcCl（NO）（SC5H4N）（PPH3）2和TC（NO）（SC5H4N）2（PPH3）
7. The preparation, characterization, and crystal and molecular structure of oxobis(ethan-1,2-dithiolato-S,µS′)technetium(V)oxo(ethan- 1,2-dithiolato-S,S′)technetium(V) (TcO)2(SCH2CH2S)3. A Tc(V) compound containing metal—sulfur—metal bridges [O] . A. Davison, B. V. DePamphilis, R. Faggiani, 1985

机译：氧比（Ethan-1,2-二噻唑胺-S，μS'）氧代（乙烯 - 1,2-二硫代噻唑胺-S，S'）Technetium（V）的制备，表征和晶体结构和晶体结构和晶体结构（TCO）2（SCH2CH2S）3。含有金属 - 硫 - 金属桥的TC（V）化合物
8. Synthesis, Radiochromatography and Biodistribution of Tc99m-Hexakis-(Methoxyisonitrile)-Technetium(I) Complexes [R] . Angelberger, P. , Zbiral, E. 1987

机译：Tc99m-六 - （甲氧基异腈） - 噻吩（I）配合物的合成，放射色谱和生物分布

Tc(NBCl2Ph)Cl-2(Me2PhP)(3)] and [Tc(NBH3)Cl-2(Me2PhP)(3)] - the first technetium complexes with nitrido bridges between technetium and boron [German

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