First characterization of an extended ammonium-ammonia complex (1)(infinity)[{NH4(NH3)(4)}(+)(mu-NH3)(2)] in the crystal structure of [NH4(NH3)(4)][Co(C2B9H11)(2)]center dot 2NH(3)

Rossmeier T; Korber N

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First characterization of an extended ammonium-ammonia complex (1)(infinity)[{NH4(NH3)(4)}(+)(mu-NH3)(2)] in the crystal structure of [NH4(NH3)(4)][Co(C2B9H11)(2)]center dot 2NH(3)

机译：[NH4（NH3）（4）的晶体结构中扩展的铵-氨络合物（1）（无穷大）[{NH4（NH3）（4）}（+）（mu-NH3）（2）]的首次表征] [Co（C2B9H11）（2）]中心点2NH（3）

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The compound [NH4(NH3)(4)][Co(C2B9H11)(2)] (.) 2 NH3 (1) was prepared by the reaction of Na[Co(C2B9H11)(2)] with a proton-charged ion-exchange resin in liquid ammonia. The ammoniate 1 was characterized by low temperature single-crystal X-ray structure analysis. The anionic part of the structure consists of [Co(C2B9H11)(2)](-) complexes, which are connected via C-(HH)-H-...-B dihydrogen bonds. Furthermore, 1 contains an infinite (1)(x)[{NH4(NH3)(4)}(+)(mu-NH3)(2)] cationic chain, which is formed by [NH4(NH3)(4)](+) ions linked by two ammonia molecules. The N-(HN)-N-... hydrogen bonds range from 1.92 to 2.71 Angstrom (DHA = Donor(...)Acceptor angles: 136-176degrees). Additional N-(HH)-H-...-B di-hydrogen bonds are observed ((HH)-H-...: 2.3-2.4 Angstrom).

机译：化合物[NH4（NH3）（4）] [Co（C2B9H11）（2）]（。）2 NH3（1）是通过Na [Co（C2B9H11）（2）]与质子带电离子反应制得的在液氨中交换树脂。通过低温单晶X射线结构分析来表征氨化物1。结构的阴离子部分由[Co（C2B9H11）（2）]（-）配合物组成，它们通过C-（HH）-H -...- B二氢键连接。此外，1包含由[NH4（NH3）（4）]形成的无限（1）（x）[{NH4（NH3）（4）}（+）（mu-NH3）（2）]阳离子链（+）离子由两个氨分子连接。 N-（HN）-N -...氢键的范围为1.92至2.71埃（DHA =施主（...）受体角：136-176度）。观察到另外的N-（HH）-H -...- B二氢键（（HH）-H -...：2.3-2.4埃）。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2004年第15期|共4页
作者
Rossmeier T; Korber N;
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正文语种 eng
中图分类化学;
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liquid ammonia; hydrogen bonding; low-temperature crystal structure analysis; ammonium ion; carboranes; polycations; HYDROGEN-BOND; TETRAHYDRATE; DIHYDRATE; IODIDE;

机译：液氨;氢键;低温晶体结构分析;铵离子;碳硼烷;聚阳离子;氢键;四水合物;二水合物;碘化物;

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1. First characterization of an extended ammonium-ammonia complex (1)(infinity)[{NH4(NH3)(4)}(+)(mu-NH3)(2)] in the crystal structure of [NH4(NH3)(4)][Co(C2B9H11)(2)]center dot 2NH(3) [J] . Rossmeier T, Korber N Zeitschrift fur Anorganische und Allgemeine Chemie . 2004,第15期

机译：[NH4（NH3）（4）的晶体结构中扩展的铵-氨络合物（1）（无穷大）[{NH4（NH3）（4）}（+）（mu-NH3）（2）]的首次表征] [Co（C2B9H11）（2）]中心点2NH（3）
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First characterization of an extended ammonium-ammonia complex (1)(infinity)[{NH4(NH3)(4)}(+)(mu-NH3)(2)] in the crystal structure of [NH4(NH3)(4)][Co(C2B9H11)(2)]center dot 2NH(3)

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