Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine

Heike Haller; Sebastian Riedel

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Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine

机译：聚卤素阴离子的最新发现-从溴到氟

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In this review we discuss the recent discoveries in polyhalide anion chemistry with the main focus on polybromide, -chloride, and -fluoride anions. Based on novel synthetic strategies either in ionic liquids or in neat halogens several new polyhalides of bromine and chlorine were synthesized. Beyond these discoveries the chemistry of polyfluoride monoanions is reviewed. Such species were investigated under cryogenic conditions at 4 K in conjunction with quantum-chemical calculations. In addition to these bonding and structural discussions, an overview of possible applications of such polyhalide anions is provided.

机译：在这篇综述中，我们讨论了多卤化物阴离子化学中的最新发现，主要集中在多溴化物，-氯离子和-氟离子上。基于在离子液体或纯卤素中的新型合成策略，合成了几种新的溴和氯多卤化物。除这些发现外，还对多氟单阴离子的化学性质进行了综述。结合量子化学计算，在4 K的低温条件下研究了此类物种。除了这些键合和结构讨论之外，还提供了这种多卤化物阴离子的可能应用的概述。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第7期|共11页
作者
Heike Haller; Sebastian Riedel;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Polyhalides; Interhalides; Fluorine; Bromine; Halogen chemistry;

机译：多卤化物;卤化物;氟;溴;卤素化学;

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专利

1. Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine [J] . Heike Haller, Sebastian Riedel Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第7期

机译：聚卤素阴离子的最新发现-从溴到氟
2. Full picture discovery for mixed-fluorine anion effects on high-voltage spinel lithium nickel manganese oxide cathodes [J] . Dae-wook Kim, Hiromasa Shiiba, Nobuyuki Zettsu, NPG Asia Materials . 2017,第7期

机译：全图片发现混合氟阴离子对高压尖晶石锂镍锰氧化物阴极的影响
3. Atomic fluorine anion storage emission material C12A7-F- and etching of Si and SiO2 by atomic fluorine anions [J] . Song CF, Sun JQ, Qiu SB, Chemistry of Materials: A Publication of the American Chemistry Society . 2008,第10期

机译：原子氟阴离子存储发射材料C12A7-F-以及原子氟阴离子对Si和SiO2的蚀刻
4. Plasma-Reactor Wall Interactions: Bromine-Fluorine Chemistry Duality in an Industrial Dry Etch Process [C] . M. Rizquez, A. Roussy, B. Bortoloti, Materials Research Society Meeting . 2015

机译：等离子体反应器壁相互作用：工业干蚀刻工艺中的溴 - 氟化学二元性
5. An ab initio study of XNO(y) and XPO(y) (X = Hydrogen, Fluorine, Chlorine, Bromine and y = +1, 0, -1) interstellar species. [D] . Sharma, Uttam. 2012

机译：XNO（y）和XPO（y）（X =氢，氟，氯，溴和y = + 1、0，-1）的从头算研究。
6. Synthesis of pH indicators for Cerenkov imaging by electrophilic substitution of bromine by fluorine in an aromatic system [O] . Alexander V. Kachur, Alejandro D. Arroyo, Nikaela W. Bryan, -1

机译：通过在芳族体系中用氟进行溴的亲电取代合成用于切伦科夫成像的pH指示剂
7. Full picture discovery for mixed-fluorine anion effects on high-voltage spinel lithium nickel manganese oxide cathodes [O] . Dae-wook Kim, Hiromasa Shiiba, Nobuyuki Zettsu, 2017

机译：高压尖晶石锂镍锰氧化物阴极的混合氟阴离子效应的全图发现
8. THE REACTION OF BROMINE TRIFLUORIDE AND FLUORINE TO FORM BROMINE PENTAFLUORIDE [R] . Harris E. Kluksdahl, George H. Cady 1959

机译：三氟甲烷和氟化氢反应生成溴化戊二烯的反应

Recent Discoveries of Polyhalogen Anions - from Bromine to Fluorine

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