Constructing Two Mn~(II) Coordination Polymers with 1,4-Bis(1-imidazol-yl)-2,5-dimethyl Benzene and Different Dicarboxylate Ligands: Syntheses, Crystal Structures, and Luminescent Properties

Liping Xu; Xiaoming Wang

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Constructing Two Mn~(II) Coordination Polymers with 1,4-Bis(1-imidazol-yl)-2,5-dimethyl Benzene and Different Dicarboxylate Ligands: Syntheses, Crystal Structures, and Luminescent Properties

机译：用1,4-双（1-咪唑基）-2,5-二甲基苯和不同的二羧酸盐配体构建两种Mn〜（II）配位聚合物：合成，晶体结构和发光性能

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Two new coordination polymers, [Mn(tda)(bimb)_(0.5)]_n (1) and [Mn(obb)(bimb)]_n (2) [H_2tda = 2,5-thiophenedicarboxylic acid, H_2obb = 4,4′-oxybis(benzoic acid) and bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene], were hydrothermally synthesized by reactions of Mn~(II) salt with a rigid ligand 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene and dicarboxylate ligands. Complex 1 exhibits an unusual binodal (3,7)-connected three-dimensional (3D) architecture with point symbol (4~4.6~(17)).(6~3). Complex 2 is a three-dimensional structure with pcu topology. Furthermore, the luminescent properties of complexes 1 and 2 are investigated.

机译：两种新的配位聚合物[Mn（tda）（bimb）_（0.5）] _ n（1）和[Mn（obb）（bimb）] _ n（2）[H_2tda = 2,5-噻吩二甲酸，H_2obb = 4，通过Mn〜（II）盐与刚性配体1的反应水热合成4'-氧双（苯甲酸）和bimb = 1,4-双（1-咪唑基）-2,5-二甲基苯]。 4-双（1-咪唑基）-2,5-二甲基苯和二羧酸酯配体。复合体1展示了一个不寻常的，与点数（3,7）连接的三维（3D）结构，其点符号为（4〜4.6〜（17））。（6〜3）。复合体2是具有pcu拓扑的三维结构。此外，研究了配合物1和2的发光性质。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2014年第9期|共4页
作者
Liping Xu; Xiaoming Wang;
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正文语种 eng
中图分类化学;
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Crystal structure; Manganese; Hydrothermal synthesis;

机译：晶体结构锰水热合成;

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1. Constructing Two Mn~(II) Coordination Polymers with 1,4-Bis(1-imidazol-yl)-2,5-dimethyl Benzene and Different Dicarboxylate Ligands: Syntheses, Crystal Structures, and Luminescent Properties [J] . Liping Xu, Xiaoming Wang Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第8a9期

机译：用1,4-双（1-咪唑基）-2,5-二甲基苯和不同的二羧酸盐配体构建两种Mn〜（II）配位聚合物：合成，晶体结构和发光性能
2. Two New Zn(II) Coordination Polymers Based on the 1,4-bis(1-imidazol-yl) -2,5-dimethyl Benzene and/or Dicarboxylate Ligands [J] . Feng Guo Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2014,第6a8期

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3. Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl)methyl)benzene: Syntheses, crystal structures and luminescent properties [J] . Liu G.-X., Xu Y.-Y., Wang Y., Inorganica Chimica Acta . 2010,第14期

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Constructing Two Mn~(II) Coordination Polymers with 1,4-Bis(1-imidazol-yl)-2,5-dimethyl Benzene and Different Dicarboxylate Ligands: Syntheses, Crystal Structures, and Luminescent Properties

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