An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties

Monte-Perez Ines; Kundu Subrata; Ray Kallol

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An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties

机译：开壳自旋单线态铜-镍中间键结合氧化还原无害金属离子：金属离子的路易斯酸度对光谱和反应性能的影响

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The yield of the Lewis acid adducts of a copper-tosylnitrene intermediate and their decay are dependent on the Lewis acidity of the redox innocent metal ions. Surprisingly, however, their spectroscopic properties and reactivity in nitrene transfer reaction with PPh3 are independent of the nature of the Lewis acid used. The result provides some new insights into the structure and reactivity of the Lewis-acid bound copper nitrene complexes.

机译：铜-对甲苯二甲苯中间体的路易斯酸加合物的产率及其衰变取决于氧化还原无毒金属离子的路易斯酸度。然而，令人惊讶地，它们的光谱性质和与PPh 3的腈转移反应中的反应性与所使用的路易斯酸的性质无关。该结果为路易斯酸结合的铜氮烯配合物的结构和反应性提供了一些新见解。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第1期|共5页
作者
Monte-Perez Ines; Kundu Subrata; Ray Kallol;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Copper; Nitrene; Nitrene transfer; Lewis acids;

机译：铜;硝基;硝基转移;路易斯酸;

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1. An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties [J] . Monte-Perez Ines, Kundu Subrata, Ray Kallol Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第1期

机译：开壳自旋单线态铜-镍中间键结合氧化还原无害金属离子：金属离子的路易斯酸度对光谱和反应性能的影响
2. Spectroscopically Resolved Binding Sites for the Adsorption of Sarin Gas in a Metal-Organic Framework: Insights beyond Lewis Acidity [J] . Harvey Jacob A., McEntee Monica L., Garibay Sergio J., Journal of physical chemistry letters . 2019,第17期

机译：用于在金属 - 有机框架中吸附Sarin气体的光谱分析结合位点：超越路易斯酸度的见解
3. Spectroscopic Capture and Reactivity of a Low-Spin Gobalt(IV)-Oxo Complex Stabilized by Binding Redox-inactive Metal Ions [J] . Seungwoo Hong, Florian F. Pfaff, Eunji Kwon Angewandte Chemie . 2014,第39期

机译：结合氧化还原非活性金属离子稳定的低旋Gobalt（IV）-Oxo络合物的光谱捕获和反应性
4. Relationship between Second Hyperpolarizability and Diradical Character in Open-Shell Singlet Metal-Metal Multiply Bonded Systems [C] . Hitoshi Fukui, Edith Botek, Beno?t Champagne, International Conference of Computational Methods in Sciences and Engineering . 2015

机译：开壳单态金属 - 金属倍增系统中第二超极化性与Diradical特性的关系
5. Exploration of Alkyne-bridged Multi[(Porphinato)metal] Oligomers for Charge Transport Applications and Spin-Spin Exchange Coupling Properties Using Synthetic, Spectroscopic, Potentiometric, and Magnetic Resonance Methods [D] . Wang, Ruobing. 2017

机译：使用合成，光谱，电位测量和磁共振方法的电荷运输应用和旋转自旋交换偶联性能的醇酸桥多[（PORPHINATO）金属]低聚物的探索
6. Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions [O] . Seungwoo Hong, Florian Felix Pfaff, Eunji Kwon, -1

机译：结合氧化还原非活性金属离子稳定的低旋钴（IV）-氧配合物的光谱捕获和反应性
7. How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo OO Bond Cleavage, and Reactivity [O] . -1

机译：金属离子路易斯酸度和空间特性如何影响二恶英结合的屏障，过氧化织物键粘合和反应性

An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties

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