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RbBrF4 Revisited

机译:再谈RbBrF4

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摘要

Rubidium tetrafluoridobromate(III) was synthesized and structurally characterized. The compound is isotypic to sodium and potassium tetrafluoridobromate( III), and crystallizes in the tetragonal space group I4/mcm (tI24, KBrF4 structure type) with a = 6.3718(2), c = 11.4934(3) angstrom, V = 466.63(2) angstrom(3), Z = 4, at T = 293 K. Additionally we investigated the compound by means of IR and Raman spectroscopy as well as theoretical studies. The data obtained by quantum chemical calculations confirm the crystal structure, and also the atomic distances and angles with an average deviation of 2.2 to 2.7%.
机译:合成了四氟溴酸(III)并对其结构进行了表征。该化合物与四氟溴酸钠(III)钠和钾同型,并在I4 / mcm(tI24,KBrF4结构类型)的四方空间群中结晶,a = 6.3718(2),c = 11.4934(3)埃,V = 466.63( 2)埃(3),Z = 4,T = 293K。此外,我们通过红外光谱和拉曼光谱以及理论研究对化合物进行了研究。通过量子化学计算获得的数据证实了晶体结构,以及原子距离和原子角,其平均偏差为2.2至2.7%。

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