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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Ammine Complexes of Na-, Ag-, Mn-, and Zn-Azides
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Ammine Complexes of Na-, Ag-, Mn-, and Zn-Azides

机译:Na,Ag,Mn和Zn叠氮化物的胺配合物

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The synthesis of ammine metal azides is achieved through a simple route in liquid ammonia solution. Azides of silver, sodium, manganese, and zinc were obtained as ammine complexes from liquid ammonia and the solid compounds were characterized. The NH3 solutions were investigated by means of NMR spectroscopy as well. The triamminesilver(I) azide as well as the unusual tetraamminesilver(I) and pentaamminesodium(I) azides are presented. The structures of the hexaamminemanganese(II) and hexaamminezinc(II) azides, which crystallize with four ammonia molecules of solvation, are elucidated. From these compounds the binary azides Mn(N-3)(2) and Zn(N-3)(2) were obtained by (careful) heating.
机译:氨金属叠氮化物的合成是通过在液氨溶液中的简单路线实现的。从液态氨中以胺配合物的形式得到了银,钠,锰和锌的叠氮化物,并对固体化合物进行了表征。 NH 3溶液也通过NMR光谱法研究。介绍了叠氮化三胺银(I)以及不寻常的叠氮化四胺银(I)和五叠氮化钠(I)。阐明了六氨合锰(II)和六氨合锌(II)叠氮化物的结构,它们通过四个氨化的溶剂化分子结晶。通过(仔细)加热,从这些化合物中获得二元叠氮化物Mn(N-3)(2)和Zn(N-3)(2)。

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