...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Two Energetic Ionic Salts of en center dot PA center dot H2O and en center dot TNR: Preparation, Structural Characterization, and Properties
【24h】

Two Energetic Ionic Salts of en center dot PA center dot H2O and en center dot TNR: Preparation, Structural Characterization, and Properties

机译：中心点PA中心点H2O和中心点TNR的两种高能离子盐：制备，结构表征和性质

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Energetic salts of en center dot PA center dot H2O and en center dot TNR were synthesized by using ethylenediamine and picric acid (PA) or 2,4,6-trinitroresorcinol (TNR) as raw materials, and their structures were characterized by elemental analysis and FT-IR spectroscopy. Single crystals of the title salts were obtained and their structures were determined by single-crystal X-ray diffraction. The thermal decomposition behaviors were investigated by DSC and TG-DTG technologies, furthermore the non-isothermal kinetic parameters and enthalpies of formation for the salts were calculated. Their combustion heats were measured by oxygen bomb calorimetry and their enthalpies of formation were also calculated based on the combustion heat data. In addition, the detonation pressure (P) and detonation velocities (D) of the salts were predicted by using the K-J equations. The results indicated that the title salts have potential applications in the field of energetic materials.
机译：以乙二胺和苦味酸（PA）或2,4,6-三硝基间苯二酚（TNR）为原料合成了中心点PA中心点H2O和中心点TNR的含能盐，并通过元素分析和结构表征。傅立叶变换红外光谱。获得标题盐的单晶，并通过单晶X射线衍射确定其结构。通过DSC和TG-DTG技术研究了热分解行为，并计算了盐的非等温动力学参数和形成焓。通过氧弹量热法测量了它们的燃烧热，并且还基于燃烧热数据计算了它们的形成焓。此外，使用K-J方程预测了盐的爆震压力（P）和爆震速度（D）。结果表明标题盐在高能材料领域具有潜在的应用。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号