Pr30Ti24I8O25Se58: A highly symmetric structure with isolated [Ti-6(O)Se-8]-cluster units [German]

Person H.; Urland W.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Pr30Ti24I8O25Se58: A highly symmetric structure with isolated [Ti-6(O)Se-8]-cluster units [German]

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Pr30Ti24I8O25Se58: A highly symmetric structure with isolated [Ti-6(O)Se-8]-cluster units [German]

机译：Pr30Ti24I8O25Se58：具有独立的[Ti-6（O）Se-8]簇单元的高度对称结构[德语]

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Black crystals of Pr30Ti24I8O25Se58 have been prepared by the reaction of Pr2Se3, Pr2O2Se, TiSe2-x, and I-2 at 900 degrees C. Its crystal structure can be described as a variation of the NaCl structure type (space group Fm (3) over bar m, a = 2319.91(15) pm, Z = 4). The compound contains the first example of a [Ti-6(O)Se-8] cluster. These clusters form a cubic close packing, where the octahedral and tetrahedral holes are occupied by "superoctahedral" and "supertetrahedral" building units, respectively. [References: 20]

机译：Pr30Ti24I8O25Se58的黑色晶体是通过Pr2Se3，Pr2O2Se，TiSe2-x和I-2在900摄氏度下的反应制备的。其晶体结构可以描述为NaCl结构类型的变化（空间群Fm（3） bar m，a = 2319.91（15）pm，Z = 4）。该化合物包含[Ti-6（O）Se-8]团簇的第一个例子。这些簇形成立方密堆积，其中八面体和四面体孔分别被“超八面体”和“超四面体”建筑单元占据。 [参考：20]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2000年第8期|共3页
作者
Person H.; Urland W.;
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正文语种 ger
中图分类化学;
关键词
Cluster compounds; Titanium; Praseodymium; Lanthanides; Clusters;

机译：簇状化合物;钛;P;镧系元素;簇;

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1. Pr30Ti24I8O25Se58: A highly symmetric structure with isolated [Ti-6(O)Se-8]-cluster units [German] [J] . Person H., Urland W. Zeitschrift fur Anorganische und Allgemeine Chemie . 2000,第8期

机译：Pr30Ti24I8O25Se58：具有独立的[Ti-6（O）Se-8]簇单元的高度对称结构[德语]
2. Electronic structures of highly symmetrical compounds of f elements. 36 - Parametric analysis of the optical spectra of an oriented tris(hydrotris(1-pyrazolyl)borato)praseodymium(III) single crystal [German] [J] . Amberger HD., Reddmann H., Apostolidis C., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第1期

机译：f元素高度对称的化合物的电子结构。 36-定向的三（氢三（1-吡唑基）硼酸酯）bor（III）单晶的光谱参数分析[德国]
3. Energetics and structures of the initial stages of nucleation of (SiO2)_N species:possible routes to highly symmetrical tetrahedral clusters [J] . Stefan T.Bromley, Francesc Illas Physical chemistry chemical physics: PCCP . 2007,第9期

机译：（SiO2）_N物种成核初始阶段的能量学和结构：可能的途径为高度对称的四面体簇
4. Highly Scalable NAND Flash Memory with Robust Immunity to Program Disturbance Using Symmetric Inversion-Type Source and Drain Structure [C] . Chang-Hyun Lee, Jungdal Choi, Youngwoo Park, Symposium on VLSI Technology . 2008

机译：高度可扩展的NAND闪存，使用对称反转型源和漏极结构进行稳健的抗扰度来编程干扰
5. Rationalizing structure, stability, and chemical bonding of pure and doped clusters, isolated and solvated multiply charged anions, and solid-state materials. [D] . Sergeeva, Alina P. 2012

机译：使纯和掺杂簇，孤立和溶剂化的多电荷阴离子以及固态材料的结构，稳定性和化学键合合理化。
6. Structures of a highly variable cell‐wall anchored protein‐encoding the spj gene from ST8/SCCmecIVl community‐associated methicillin‐resistant Staphylococcus aureus (CA‐MRSA/J) isolated from 2003 onwards: An indicator of a strongly invasive pathotype [O] . Tsai‐Wen Wan, Lee‐Jene Teng, Tatsuo Yamamoto -1

机译：从2003年开始分离的编码ST8 / SCCmecIVl社区相关的耐甲氧西林金黄色葡萄球菌（CA-MRSA / J）的spj基因的高度可变的细胞壁锚定蛋白的结构：
7. Bonding and Oxidation State of a Transition Metal Atom Encapsulated in an Isolated Octahedral Cluster Cation of Main Group Elements: Synthesis, Crystal Structure and Electronic Structure of Pt2In14Ga3O8F15 Containing Highly Positive 18 [O] . -1

机译：过渡金属原子的粘合和氧化状态包封在主要群体元素的分离的八面体聚类阳离子中：PT2IN14GA3O8F15的合成，晶体结构和电子结构含有高阳性18

Pr30Ti24I8O25Se58: A highly symmetric structure with isolated [Ti-6(O)Se-8]-cluster units [German]

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