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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >About RhSCl5 - A hexameric, molecular rhodium(III) complex with SCl2 ligands [German]
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About RhSCl5 - A hexameric, molecular rhodium(III) complex with SCl2 ligands [German]

机译:关于RhSCl5-具有SCl2配体的六聚体分子铑(III)配合物[德语]

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摘要

Needle-shaped red crystals of RhSCl5 were obtained by reaction of Rh metall or RhI3 with SCl2 in a closed silica ampoule. In the monoclinic crystal structure the Rh atoms are octahedrally coordinated by 5 Cl atoms and a SCl2 ligand. In each case six RhCl5(SCl2) groups are connected with each other by two common edges of Cl atoms to form hexameric molecules [RhCl3(SCl2)](6). In the pseudohexagonal unit cell (monoclinic, space group C2/c, a = 26.215(5) Angstrom, b = 6.7750(10) Angstrom, c = 26.868(5) Angstrom, beta = 119.06(3)degrees, Z = 4) the molecules are stacked in columns and form a hexagonal rod package. [References: 21]
机译:Rh金属或RhI3与SCl2在密闭的二氧化硅安瓿瓶中反应,得到RhSCl5的针状红色晶体。在单斜晶体结构中,Rh原子由5个Cl原子和一个SCl2配体八面体配位。在每种情况下,六个RhCl5(SCl2)基团通过Cl原子的两个公共边缘相互连接,以形成六聚体分子[RhCl3(SCl2)](6)。在伪六边形晶胞中(单斜晶系,空间群C2 / c,a = 26.215(5)埃,b = 6.7750(10)埃,c = 26.868(5)埃,beta = 119.06(3)度,Z = 4)分子堆积成列,形成六角棒状包装。 [参考:21]

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