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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >SYNTHESES AND CRYSTAL STRUCTURES OF THE ZINCATES [NA(12-CROWN-4)(2)][ZN(N(SIME3)(2))(3)] AND [NA(12-CROWN-4)(2)](2)[ZN(C-C-PH)(3)(THF)][ZN(C-C-PH)(3)] [German]
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SYNTHESES AND CRYSTAL STRUCTURES OF THE ZINCATES [NA(12-CROWN-4)(2)][ZN(N(SIME3)(2))(3)] AND [NA(12-CROWN-4)(2)](2)[ZN(C-C-PH)(3)(THF)][ZN(C-C-PH)(3)] [German]

机译:锌[NA(12-CROWN-4)(2)] [ZN(N(SIME3)(2))(3)]和[NA(12-CROWN-4)(2)]的合成和晶体结构2)[ZN(CC-PH)(3)(THF)] [ZN(CC-PH)(3)] [德语]

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摘要

The homoleptic amido complex [Na(12-crown-4)(2)][Zn{N(SiMe3)(2)}(3)] (1) is Prepared from Zn[N(SiMe3)(2)](2) and NaN(SiMe3)(2) in toluene solution in the presence of 12-crown-4. Single crystals of 1.0.5 C6H14 can be obtained from diethylether/hexane solutions. 1 reacts with phenylacetylene to give [Na(12-crown-4)(2)][Zn(C=C-Ph)(3)] (2) which forms single crystals 2.0.5 THF from tetrahydrofurane solutions. The complexes were characterized by IR spectroscopy and by crystal structure determinations. [References: 21]
机译:由Zn [N(SiMe3)(2)](2)制备均酰胺基络合物[Na(12-crown-4)(2)] [Zn {N(SiMe3)(2)}(3)](1) )和NaN(SiMe3)(2)在甲苯溶液中于12冠4存在下。可以从二乙醚/己烷溶液中获得1.0.5 C6H14的单晶。 1与苯乙炔反应生成[Na(12-crown-4)(2)] [Zn(C = C-Ph)(3)](2),其由四氢呋喃溶液形成单晶2.0.5 THF。通过红外光谱和晶体结构测定来表征配合物。 [参考:21]

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