PHOSPHANEIMINE AND PHOSPHORANEIMINATO COMPLEXES OF MAGNESIUM - THE CRYSTAL STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], [MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8 [German]

Muller A.; Neumuller B.; Dehnicke K.; Magull J.; Krieger M.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >PHOSPHANEIMINE AND PHOSPHORANEIMINATO COMPLEXES OF MAGNESIUM - THE CRYSTAL STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], [MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8 [German]

【24h】

PHOSPHANEIMINE AND PHOSPHORANEIMINATO COMPLEXES OF MAGNESIUM - THE CRYSTAL STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], [MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8 [German]

机译：磷酸的膦亚胺和磷亚胺络合物-[MGBR1,25I0,75（ME3SINPME3）（OET2）]，[MGI2（ME3SINPME3）（2）]，[MG2I2（ME3MENPME2CH2）（ME2SIOCH））的晶体结构]和[MGBR（NPME3）]（4）CENTER-DOT-C7H8 [德语]

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

By reactions of the silylated phosphaneimine Me3SiNPMe3 with the Grignard reagents EtMgBr and MeMgI, respectively, the carbanionic phosphoraneiminato derivatives [XMg(CH2PMe2NSiMe3)](n) (X=Br, I) can be isolated as main products. The by-products of these reactions, [MgBr1,25I0,75(Me3SiNPMe3)(OEt2)], [MgI2(Me3SiNPMe3)(2)] and [Mg2I2(CH2PMe2NSiMe3)(O(Me)CHCH2PMe2NSiMe3)(OEt2)] were identified by crystal structure determinations. The phosphoraneiminato complex [MgBr(NPMe3)(4) . C7H8 with hetero cubane structure is formed by a metathesis reaction of [ZnBr(NPMe3)](4) with RMgBr (R = Ph, Mes). [References: 38]

机译：通过使甲硅烷基化的膦亚胺Me3SiNPMe3分别与格氏试剂EtMgBr和MeMgI反应，可以分离出作为主要产物的碳负离子亚磷酰胺基衍生物[XMg（CH2PMe2NSiMe3）]（n）（X = Br，I）。确定了这些反应的副产物[MgBr1,25I0,75（Me3SiNPMe3）（OEt2）]，[MgI2（Me3SiNPMe3）（2）]和[Mg2I2（CH2PMe2NSiMe3）（O（Me）CHCH2PMe2NSiMe3）（OEt2）]。通过晶体结构测定。磷亚胺基络合物[MgBr（NPMe3）（4）。通过[ZnBr（NPMe3）]（4）与RMgBr（R = Ph，Mes）的复分解反应形成具有杂配古巴结构的C7H8。 [参考：38]

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第7期|共7页
作者
Muller A.; Neumuller B.; Dehnicke K.; Magull J.; Krieger M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 ger
中图分类化学;
关键词
Magnesium compounds; Phosphoraneiminato complexes; Crystal structures; Heterocubane structure;

机译：镁化合物;磷亚胺络合物;晶体结构;异库仑结构;

相似文献

外文文献

1. PHOSPHANEIMINE AND PHOSPHORANEIMINATO COMPLEXES OF MAGNESIUM - THE CRYSTAL STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], [MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8 [German] [J] . Muller A., Neumuller B., Dehnicke K., Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第7期

机译：磷酸的膦亚胺和磷亚胺络合物-[MGBR1,25I0,75（ME3SINPME3）（OET2）]，[MGI2（ME3SINPME3）（2）]，[MG2I2（ME3MENPME2CH2）（ME2SIOCH））的晶体结构]和[MGBR（NPME3）]（4）CENTER-DOT-C7H8 [德语]
2. Phosphoraneiminato- and phosphaneimine complexes of Nickel(II). Crystal structures of [Ni(O3SCF3) (NPMe3)] (4) [Ni4Br5{NP(NMe2)(3)}(3)], [NiBr2{HNP(NMe2)(3)}(2)], and [Ni(PMePh2)(4)] [German] [J] . Krieger M., Harms K., Greiner A., Zeitschrift fur Anorganische und Allgemeine Chemie . 2001,第4期

机译：镍（II）的磷亚胺基和膦亚胺配合物。 [Ni（O3SCF3）（NPMe3）]（4）[Ni4Br5 {NP（NMe2）（3）}（3）]，[NiBr2 {HNP（NMe2）（3）}（2）]和[Ni的晶体结构（PMePh2）（4）] [德语]
3. PHOSPHORANEIMINATO COMPLEXES OF BORON - SYNTHESES AND CRYSTAL STRUCTURES OF [BBR2(NPME3)](2), [B2BR3((NPPR3)-PR-I)(2)]BR, [B-2(NPET3)(4)]BR-2, [B2BR2(NPPH3)(3)]BBR4 AND [(B-2(NME2)(2))(2)(NPET3)(2)]CL-2 [German] [J] . Mohlen M., Faza N., Muller C., Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第10期

机译：硼的磷亚胺络合物-[BBR2（NPME3）]（2），[B2BR3（（NPPR3）-PR-I）（2）] BR，[B-2（NPET3）（4）] BR-的合成和晶体结构2，[B2BR2（NPPH3）（3）] BBR4和[[B-2（NME2）（2））（2）（NPET3）（2）] CL-2 [德语]

PHOSPHANEIMINE AND PHOSPHORANEIMINATO COMPLEXES OF MAGNESIUM - THE CRYSTAL STRUCTURES OF [MGBR1,25I0,75(ME3SINPME3)(OET2)], [MGI2(ME3SINPME3)(2)], [MG2I2(ME3SINPME2CH2)(ME3SINPME2CH2CH(ME)O)(OET2)], AND [MGBR(NPME3)](4)CENTER-DOT-C7H8 [German]

摘要

著录项

相似文献

相关主题

期刊订阅