SYNTHESIS AND STRUCTURE INVESTIGATIONS ON IODOCUPRATES(I) .17. CRYSTAL STRUCTURES OF POLYMERIC IODO-THIOCYANATO METALLATES(I) WITH HETEROCUBANE-LIKE STRUCTURE UNITS - [(C2H5)(4)N+](2)(3)(INFINITY)[CU4I4(SCN)(4/2)(2-)]CENTER-DOT-2(CH3)(2)CO AND [(C2H5

Rudolph LN.; Hartl H.

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SYNTHESIS AND STRUCTURE INVESTIGATIONS ON IODOCUPRATES(I) .17. CRYSTAL STRUCTURES OF POLYMERIC IODO-THIOCYANATO METALLATES(I) WITH HETEROCUBANE-LIKE STRUCTURE UNITS - [(C2H5)(4)N+](2)(3)(INFINITY)[CU4I4(SCN)(4/2)(2-)]CENTER-DOT-2(CH3)(2)CO AND [(C2H5

机译：碘甲酸酯的合成和结构研究（I）.17。带有类似异辛烷的结构单元的聚合物碘代-硫氰酸金属盐的晶体结构（I）-[（C2H5）（4）N +]（2）（3）（无穷大）[CU4I4（SCN）（4/2）（2-） ] CENTER-DOT-2（CH3）（2）CO和[（C2H5

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The reaction of CuSCN and AgSCN with (C2H5)(4)NI in acetone results in the formation of new Iodo-thiocyanato cuprates(I) or argentates(I) with polymeric anion lattices and areas of holes in which the cations and solvent molecules are inserted. [(C2H5)(4)N+](2 infinity)(3)[Cu4I4(SCN)(4/2)(2-)] . 2(CH3)(2)CO 1 crystallizes in the monoclinic space group P2(1) with a = 1205.7(1), b = 2489.1(3), c = 1238.0(1) pm; beta = 93.04(1)degrees; V = 3710.1(8) . 10(6) pm(3); Z = 2. Two different, negatively charged heterocubane units [Cu4I4(SCN)(4/2)(2-)] are three-dimensionally connected by 1,3-mu-thiocyanato ligands forming a crystal structure with hose-shaped channels where cations and acetone molecules are placed. [(C2H5)(4)N+](2 infinity)(2)[Ag4I4(SCN)(4/2)(2-)] . (CH3)(2)CO 2 crystallized in the orthorhombic space group C222(1) with a = 1206.7(1), b = 1398.2(1), c = 2318.8(2) pm; V = 3912.4(7) . 10(6) pm(3); Z = 8. In this compound 1,3-mu-thiocyanato-bridged heterocubane units [Ag4I4(SCN)4/22-] form a layer structure with channel-shaped cavities vertical to them. Within these hollows there is again place for the cations and acetone molecules. [References: 45]

机译：CuSCN和AgSCN与（C2H5）（4）NI在丙酮中的反应导致形成新的碘代硫氰酸根合铜酸盐（I）或银酸盐（I），其具有聚合阴离子晶格和其中阳离子和溶剂分子为孔的区域已插入。 [（C2H5）（4）N +]（2无穷大）（3）[Cu4I4（SCN）（4/2）（2-）]。 2（CH3）（2）CO 1在单斜空间群P2（1）中结晶，a = 1205.7（1），b = 2489.1（3），c = 1238.0（1）pm; beta = 93.04（1）度; V ＝ 3710.1（8）。 10（6）pm（3）; Z =2。两个不同的带负电的杂配单元[Cu4I4（SCN）（4/2）（2-）]通过1,3-mu-thiocyanato配体三维连接，形成带有软管形通道的晶体结构，其中放置阳离子和丙酮分子。 [（C2H5）（4）N +]（2无穷大）（2）[Ag4I4（SCN）（4/2）（2-）]。（CH3）（2）CO 2在正交空间群C222（1）中结晶，a = 1206.7（1），b = 1398.2（1），c = 2318.8（2）pm; V ＝ 3912.4（7）。 10（6）pm（3）; Z ＝ 8。在该化合物中，1，3-μ-硫代氰基桥联的杂铜单元[Ag4I4（SCN）4 / 22-]形成具有垂直于它们的通道形腔的层结构。在这些空洞中，再次放置了阳离子和丙酮分子。 [参考：45]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第5期|共8页
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Rudolph LN.; Hartl H.;
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中图分类化学;
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Iodo-thiocyanato cuprate(i); Iodo-thiocyanato argentate(i); Crystal structure; Heterocubane type anions; Stella-quadrangula; M4x4 core; Complexes; Cubane; Tetrahedra; Cations; Chain;

机译：碘代硫氰酸根合铜酸盐（i）;碘代硫代氰酸根合盐（i）;晶体结构;杂多型阴离子;斯特拉-四边形;M4x4核;络合物;库巴烷;四面体;阳离子;链;

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机译：碘甲酸酯的合成和结构研究（I）.17。带有类似异辛烷的结构单元的聚合物碘代-硫氰酸金属盐的晶体结构（I）-[（C2H5）（4）N +]（2）（3）（无穷大）[CU4I4（SCN）（4/2）（2-） ] CENTER-DOT-2（CH3）（2）CO和[（C2H5
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SYNTHESIS AND STRUCTURE INVESTIGATIONS ON IODOCUPRATES(I) .17. CRYSTAL STRUCTURES OF POLYMERIC IODO-THIOCYANATO METALLATES(I) WITH HETEROCUBANE-LIKE STRUCTURE UNITS - [(C2H5)(4)N+](2)(3)(INFINITY)[CU4I4(SCN)(4/2)(2-)]CENTER-DOT-2(CH3)(2)CO AND [(C2H5

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