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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >MASS SPECTROMETRIC AND X-RAY STUDIES ON COMPLEXES OF THE TYPE (COD)PTX2 (X=CL, BR, I, CH3, CH2CME3, CH2SIME3) [German]
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MASS SPECTROMETRIC AND X-RAY STUDIES ON COMPLEXES OF THE TYPE (COD)PTX2 (X=CL, BR, I, CH3, CH2CME3, CH2SIME3) [German]

机译:(COD)PTX2(X = CL,BR,I,CH3,CH2CME3,CH2SIME3)复合物的质谱和X射线研究[德国]

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摘要

Investigations by mass spectrometry at complexes of the type (COD)PtX2 (X = Cl (1), Br (2), I (3), Me (4), CH2CMe3 (5) and CH2SiMe3 (6), (COD)=1,5-cyclooctadiene) show the mole peak of all compounds with the characteristic isotopic pattern of platinum and platinum with chlorine, bromine or silicon respectively. The group of peaks of the complexes 1-5 at 300 mle show a high stability of the (COD)Pt fragment. A new route of synthesis of (COD)PtBr2 (2) is described. The compounds (COD)Pt(CH2CMe3)(2) (5) and (COD)Pt(CH2SiMe3)(2) (6) were characterized by X-ray structure. [References: 27]
机译:通过质谱分析(COD)PtX2(X = Cl(1),Br(2),I(3),Me(4),CH2CMe3(5)和CH2SiMe3(6),(COD)= 1,5-环辛二烯)显示所有化合物的摩尔峰,其特征在于铂和铂分别具有氯,溴或硅的同位素特征。配合物1-5在300ml处的峰组显示(COD)Pt片段的高稳定性。描述了合成(COD)PtBr2(2)的新途径。通过X射线结构表征化合物(COD)Pt(CH2CMe3)(2)(5)和(COD)Pt(CH2SiMe3)(2)(6)。 [参考:27]

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