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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Crystal structure of mu-oxo-bis[9,22-(bisbutyloxy)hemiporphyrazinato]iron(III)
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Crystal structure of mu-oxo-bis[9,22-(bisbutyloxy)hemiporphyrazinato]iron(III)

机译:mu-氧代双[9,22-(双丁氧基)半卟啉锌]铁(III)的晶体结构

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摘要

The crystal structure of the title compound, C68H60N16O5Fe2, shows a dinuclear complex of two crystallographically independent, distorted hemiporphrazinato iron complexes with five-coordinate iron and oxygen as bridging ligand. The Fe1-O1-Fe2 angle is 151.16 degrees, the Fe-O bond lengths are Fe1-O1 [1.771(2) angstrom] and Fe2-O1 [1.773(2) angstrom]. The dinuclear complexes have a staggered conformation with a dihedral angle of 26.2 degrees, but coaxially to form tetrameric units is not observed. The molecule is characterized by short Fe-N (isoindole) bonds [1.998(3) angstrom] and long Fe-N (pyridine) bonds, values range from [2.175(3) angstrom] to [2.245(3) angstrom].
机译:标题化合物C68H60N16O5Fe2的晶体结构显示双核络合物,由两个晶体学独立的,扭曲的半卟啉铁络合物组成,具有五配位的铁和氧作为桥联配体。 Fe1-O1-Fe2角为151.16度,Fe-O键长为Fe1-O1 [1.771(2)埃]和Fe2-O1 [1.773(2)埃]。双核复合物具有交错构型,具有26.2度的二面角,但是未观察到同轴形成四聚体单元。该分子的特征是短的Fe-N(异吲哚)键[1.998(3)埃和长的Fe-N(吡啶)键,值从[2.175(3)埃到[2.245(3)埃]。

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