The 3D supramolecular compound {[Cu-2(L-val)(2)(4,4 '-bipy)(H2O)(2)](NO3)(2)}(n) (L-val = L-valine anion, 4,4 '-bipy=4,4 '-bipyridine)

Lou BY; Huang XD; Lin XC

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The 3D supramolecular compound {[Cu-2(L-val)(2)(4,4 '-bipy)(H2O)(2)](NO3)(2)}(n) (L-val = L-valine anion, 4,4 '-bipy=4,4 '-bipyridine)

机译：3D超分子化合物{[Cu-2（L-val）（2）（4,4'-bipy）（H2O）（2）]（NO3）（2）}（n）（L-val = L-缬氨酸阴离子，4,4'-联吡啶= 4,4'-联吡啶）

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{[Cu-2(L-val)(2)(4,4'-bipy)(H2O)(2)](NO3)(2)}(n) was synthesized and its crystal structure was determined by X-ray diffraction. In the presence of 4,4'-bipyridine, deprotoned L-valine chelates Cu-II ions into coordination layers which were linked into a framework by hydrogen-bonded chains resulting from nitrate anions and water molecules.

机译：合成{[Cu-2（L-val）（2）（4,4'-bipy）（H2O）（2）]（NO3）（2）}（n）并通过X射线确定其晶体结构衍射。在存在4,4'-联吡啶的情况下，去质子化的L-缬氨酸螯合Cu-II离子进入配位层，这些配位层通过由硝酸根阴离子和水分子形成的氢键链连接到骨架中。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2007年第3期|共3页
作者
Lou BY; Huang XD; Lin XC;
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正文语种 eng
中图分类化学;
关键词
copper; amino acids; hydrogen bonding; COORDINATION POLYMERS; MOLECULES; DESIGN; NETWORKS; CHAINS; HELIX;

机译：铜;氨基酸;氢键;配位聚合物;分子;设计;网络;链;螺旋;

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1. The 3D supramolecular compound {[Cu-2(L-val)(2)(4,4 '-bipy)(H2O)(2)](NO3)(2)}(n) (L-val = L-valine anion, 4,4 '-bipy=4,4 '-bipyridine) [J] . Lou BY, Huang XD, Lin XC Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第3期

机译：3D超分子化合物{[Cu-2（L-val）（2）（4,4'-bipy）（H2O）（2）]（NO3）（2）}（n）（L-val = L-缬氨酸阴离子，4,4'-联吡啶= 4,4'-联吡啶）
2. Self-assembled H-bonded supramolecular interactions in monomeric complex [Mg(H2O)(6)]center dot L-2 center dot 2bipy center dot H2O; [LH=2-amino-5-nitrobenzoic acid, bipy=4,4 '-bipyridine]]]]: Joint theoretical calculations and Hirshfeld surface analysis [J] . Mudsainiyan Rahul Kumar, Jassal Amanpreet Kaur, Islam Nasarul Journal of Molecular Structure . 2021,第1期

机译：单体复合物中的自组装H键合超分子相互作用[Mg（H2O）（6）]中心点L-2中心点2bipy中心点H2O; [LH = 2-氨基-5-硝基苯甲酸，BiPY = 4,4'-脂吡啶]]]：联合理论计算和HIRSHFELD表面分析
3. Structural analysis and magnetic properties of the 1D [Fe(dca)(2)bipy(H2O)]center dot 1/2H(2)O and the 3D [Ni(dca)(2)bipy] (dca = dicyanamide; bipy=4,4 '-bipyridine) [J] . Martin S., Barandika MG., Ezpeleta JM., Journal of the Chemical Society. Dalton Transactions . 2002,第22期

机译：1D [Fe（dca）（2）bipy（H2O）]中心点1 / 2H（2）O和3D [Ni（dca）（2）bipy]（dca =双氰胺; bipy = 4,4'-联吡啶）
4. Synthesis, Crystal Structure of a Twin-Nest-Shaped Cluster Compound,Mo_2O_2S_6Cu_6I_2(4,4'-bipy)_3_n [C] . Yan Xu, Yunbiao Sun, Yimin Wu International Conference on Chemical Engineering and Advanced Materials . 2014

机译：合成，双巢形簇化合物的晶体结构，mo_2o_2s_6cu_6i_2（4,4'-bipy）_3 _n
5. Spectroscopic and Electrochemical Studies of [Ru(1,10-phenanthroline) 2(4,4'- dihydroxy-2,2'-bipyridine)]2+ and Related Complexes. [D] . Kuhn, Ashley E. 2017

机译：[Ru（1,10-phenothroline）2（4,4'-dihydroxy-2,2'-bipyridine）] 2+及其相关配合物的光谱和电化学研究。
6. Synthesis Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 22-Dimethylpentanedioic Acid(2dmepdaH2) and 33-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of Cu(3dmepda)(bipy)2· 6H2O and Cu(2dmepda)(bipy)(EtOH)2· 4EtOH(bipy = 22′Bipyridine) [O] . Michael Devereux, Malachy McCann, Denis OShea, 2006

机译：22-二甲基戊二酸（2dmepdaH2）和33-二甲基戊二酸（3dmepdaH2）的金属配合物的合成超氧化物歧化酶模拟和抗癌活性：Cu（3dmepda）（bipy） 2·6H2O的X射线晶体结构和Cu（2dmepda）（bipy）（EtOH） 2·4EtOH（Bipy = 22联吡啶）
7. Synthesis, Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 2,2-Dimethylpentanedioic Acid(2dmepdaH2) and 3,3-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of [Cu(3dmepda)(bipy)]2· 6H2O and [Cu(2dmepda)(bipy)(EtOH)]2· 4EtOH (bipy = 2,2′Bipyridine) [O] . Devereux, Michael, McCann, Malachy, O'Shea, Denis, 2006

机译：2,2-二甲基戊二酸（2dmepdaH2）和3,3-二甲基戊二酸（3dmepdaH2）的金属配合物的合成，超氧化物歧化酶模拟和抗癌活性：[Cu（3dmepda）（bipy）] 2·6H2O的X射线晶体结构和[Cu（2dmepda）（bipy）（EtOH）] 2·4EtOH （Bipy = 2,2'联吡啶）
8. Sub-Picosecond Injection of Electrons from Excited (Ru (2,2'-bipy-4,4'- dicarboxy)2(SCN)2) into TiO2 Using Transient Mid-Infrared Spectroscopy [R] . A.J. Nozik, H.N. Ghosh, J.B. Asbury, 1999

机译：瞬态中红外光谱法将激发的（Ru（2,2'-bipy-4,4'-二羧基）2（sCN）2）电子亚皮秒注入TiO2

The 3D supramolecular compound {[Cu-2(L-val)(2)(4,4 '-bipy)(H2O)(2)](NO3)(2)}(n) (L-val = L-valine anion, 4,4 '-bipy=4,4 '-bipyridine)

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