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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Anhydrous mercurous chlorate, Hg-2(ClO3)(2)
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Anhydrous mercurous chlorate, Hg-2(ClO3)(2)

机译:无水氯酸汞Hg-2(ClO3)(2)

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摘要

Colourless single crystals of the anhydrous mercurous chlorate were grown from a solution of mercuric oxide (HgO) in chloric acid (HClO3) in the presence of elemental mercury. The crystal structure (monoclinic, P2(1), Z = 4, a = 816.59(12), b = 641.02(5), c = 1290.3(2) pm, beta = 97.506(12)degrees, R(all) = 0.0317) contains trans-O2ClO-Hg-Hg-OClO2 molecules with a Hg-Hg distance of 251.03(4) pm, Hg-O (bond) distances of 218 and 224 pm and Hg-Hg-O angles of 177 and 165degrees, respectively. [References: 8]
机译:在元素汞的存在下,从氧化汞(HgO)在氯酸(HClO3)中的溶液中生长出无水氯酸汞的无色单晶。晶体结构(单斜晶,P2(1)/ n,Z = 4,a = 816.59(12),b = 641.02(5),c = 1290.3(2)pm,β= 97.506(12)度,R(全部)= 0.0317)包含反式-O2ClO-Hg-Hg-OClO2分子,其Hg-Hg距离为251.03(4)pm,Hg-O(键)距离为218和224 pm,Hg-Hg-O角为177和分别为165度[参考:8]

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