Syntheses and characterization of mixed-anions lead(II) complexes, [Pb(phen)(2)(CH3COO)]X (X=NCS-, NO3- and ClO4-), crystal structure of [Pb(phen)(2)(CH3COO)][(ClO4)

Morsali A.; Mahjoub AR.; Darzi SJ.; Soltanian MJ.

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Syntheses and characterization of mixed-anions lead(II) complexes, [Pb(phen)(2)(CH3COO)]X (X=NCS-, NO3- and ClO4-), crystal structure of [Pb(phen)(2)(CH3COO)][(ClO4)

机译：混合阴离子铅（II）配合物[Pb（phen）（2）（CH3COO）] X（X = NCS-，NO3-和ClO4-）的合成和表征，[Pb（phen）（2）的晶体结构（CH3COO）] [（ClO4）

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The 1:2 adduct lead(II) complexes with 1,10-phenanthroline (phen) containing three different anions, [Pb(phen)(2)(CH3COO)X] (X = NCS-, NO3- and C1O(4)(-)), have been synthesized and characterized by CHN elemental analysis, IR-, H-1- and C-13 NMR spectroscopy. The structure of [Pb(phen)(2)(CH3COO)(ClO4)] was determined by single crystal X-ray analysis. The Pb atom of the monomeric complex is coordinated by four nitrogen atoms of two 1,10-phenanthroline ligands and two oxygen atoms of the acetate ligand to form an irregular octahedron. The arrangement of the 1,10-phenanthroline and acetate ligands, exhibits a coordination gap around the Pb-11 ion, possibly occupied by a stereochemical electron active lone pair on lead(II), which results in a hemidirected lead compound. The pi-pi stacking interaction between the parallel aromatic rings may help to increase the coordination 'gap' around the Pb-II ion. [References: 25]

机译：1：2加合物铅（II）与包含三种不同阴离子[Pb（phen）（2）（CH3COO）X]（X = NCS-，NO3-和C1O（4）的1,10-菲咯啉（phen）的配合物（-）），已通过CHN元素分析，IR-，H-1-和C-13 NMR光谱进行了合成和表征。通过单晶X射线分析确定[Pb（phen）（2）（CH3COO）（ClO4）]的结构。单体络合物的Pb原子由两个1,10-菲咯啉配体的四个氮原子和乙酸酯配体的两个氧原子配位，形成不规则的八面体。 1,10-菲咯啉和乙酸盐配体的排列在Pb-11离子周围显示出配位间隙，可能被铅（II）上的立体化学电子活性孤对占据，从而导致半定向的铅化合物。平行芳环之间的pi-pi堆积相互作用可能有助于增加Pb-II离子周围的配位“间隙”。 [参考：25]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2003年第14期|共4页
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Morsali A.; Mahjoub AR.; Darzi SJ.; Soltanian MJ.;
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正文语种 eng
中图分类化学;
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Lead; Crystal structure; Mixed-anions complexes; Lone pair activity; Ligand design; Metal-ions; Refinement; Chemistry; Adducts; Pair;

机译：铅;晶体结构;混合阴离子配合物;孤对活性;配体设计;金属离子;精制;化学;加合物;对;

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1. Syntheses and characterization of mixed-anions lead(II) complexes, [Pb(phen)(2)(CH3COO)]X (X=NCS-, NO3- and ClO4-), crystal structure of [Pb(phen)(2)(CH3COO)][(ClO4) [J] . Morsali A., Mahjoub AR., Darzi SJ., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第14期

机译：混合阴离子铅（II）配合物[Pb（phen）（2）（CH3COO）] X（X = NCS-，NO3-和ClO4-）的合成和表征，[Pb（phen）（2）的晶体结构（CH3COO）] [（ClO4）
2. Syntheses and characterization of two new lead(II) acetate complexes, Pb(L)(CH3COO)(2), L=2,2 ': 6 ',2 ''-terpyridine (tpy) and 2,4,6-tris(2-pyridyl)-1,3,5-triazine (trz), crystal structure of Pb(tpy)(CH3COO)(2) [J] . Morsali A Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2004,第9期

机译：两种新的乙酸铅（II）络合物Pb（L）（CH3COO）（2），L = 2,2'：6'，2''-吡啶（tpy）和2,4,6-tris的合成与表征（2-吡啶基）-1,3,5-三嗪（trz），Pb（tpy）（CH3COO）（2）的晶体结构
3. Syntheses, characterizations and crystal structures of two new complexes, [Co₂(CH₂ =C(CH₃)CO₂)₄(phen)₂(H₂O)₂] and [Pb₂(CH₂ =C(CH₃)CO₂)₄(phen)₂] [J] . Tie-Jun Caia* Wen-Jun Jianga Qian Denga Zhen-Shan Penga Yun-Fei Longa Hong Liua amp, Mei-Ling Liua Journal of Co-ordination Chemistry . 2008,第20期

机译：两种新配合物[Co _{2 （CH _{2 = C（CH _{3 ）CO _{2 < / sub>）_{4 （phen）_{2 （H _{2 O）_{2 ]和[Pb _{2 （CH _{2 = C（CH _{3 ）CO _{2 ）_{4 （phen）< sub> 2 ]}}}}}}}}}}}}}
4. PREPARATION AND CHARACTERIZATION OF Pb_2SnF_6, THE FIRST LEAD(II)-TIN(II) FLUORIDE THAT IS A SUPERSTRUCTURE OF α-PbF_2 [C] . Raimondo CALANDRINO, Anthony COLLIN, Georges DENES, Materials Research Society Symposium . 2003

机译：PB_2SNF_6的制备和表征，第一引线（II）-TIN（II）氟化物，其是α-PBF_2的超大结构
5. Organometallic photonucleases. I. DNA cleavage by the photolysis of cyclopentadienyl metal complexes: Mechanistic studies and sequence selectivity of strand scission by CpW(CO)3CH3. II. Footprinting of chromatin structure and chromatin remodeling by SWI/SNF utilizing CpW(CO)3CH3. III. Dual mechanisms of DNA damage by MoX(eta3-allyl)(CO)3(phen) complexes. [D] . Downs, Jennifer. 2005

机译：有机金属光核酸酶。 I.通过环戊二烯基金属配合物的光解来切割DNA：通过CpW（CO）3CH3进行断裂的机理研究和序列选择性。二。 SWI / SNF利用CpW（CO）3CH3进行染色质结构足迹测定和染色质重塑。三， MoX（eta3-烯丙基）（CO）3（phen）复合物对DNA的双重破坏机制。
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）
8. Synthesis,Properties,and Structural Characterization of Lead(II) Bis(Disphenylphosphinate),Pb(OP(C6H5)20)2. [R] . colamarino, p. orioli, p. l. 1975

机译：铅（II）双（二苯基次膦酸）铅（Op（C6H5）20）2的合成，性质和结构表征。

Syntheses and characterization of mixed-anions lead(II) complexes, [Pb(phen)(2)(CH3COO)]X (X=NCS-, NO3- and ClO4-), crystal structure of [Pb(phen)(2)(CH3COO)][(ClO4)

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