Synthesis and crystal structure of the hydrogen polyphosphide bis(tetraphenylphosphonium) hydrogenheptaphosphide-ammonia(1/3) (PPh4)(2)HP7 center dot 3NH(3)

Aschenbrenner AC; Korber N

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Synthesis and crystal structure of the hydrogen polyphosphide bis(tetraphenylphosphonium) hydrogenheptaphosphide-ammonia(1/3) (PPh4)(2)HP7 center dot 3NH(3)

机译：多磷化氢双（四苯基phosph）氢七磷-氨（1/3）（PPh4）（2）HP7中心点3NH（3）的合成和晶体结构

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(PPh4)(2)HP7 . 3NH(3) was prepared by the reaction of K3P7 with a proton-charged ion exchange resin in the presence of (PPh4)Br in liquid ammonia.. and characterized by low temperature X-ray structure analysis. The thermally very unstable compound contains the hydrogenheptaphosphide anion HP2-, the nortricy-clane-like cage of which is slightly distorted by the attachment of the hydrogen atom.

机译：（PPh4）（2）HP7。 3NH（3）是通过K3P7与带质子的离子交换树脂在（PPh4）Br在液氨中的存在下反应制备的，并通过低温X射线结构分析进行了表征。热非常不稳定的化合物包含七庚酸氢根阴离子HP2-，其类似鸟巢状的笼状分子由于氢原子的附着而略微变形。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2004年第1期|共2页
作者
Aschenbrenner AC; Korber N;
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正文语种 eng
中图分类化学;
关键词
phosphorus; hydrogen polyphospide; heptaphosphide; crystal structure; PHOSPHORUS; CHEMISTRY; HEPTAPHOSPHIDE; SALT;

机译：磷;多磷化氢;七磷;晶体结构;磷;化学性质;庚二酚;盐;

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Synthesis and crystal structure of the hydrogen polyphosphide bis(tetraphenylphosphonium) hydrogenheptaphosphide-ammonia(1/3) (PPh4)(2)HP7 center dot 3NH(3)

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