Hydrothermal synthesis of rare earth iodates from the corresponding periodates: II. Synthesis and structures of Ln(IO3)(3) (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO3)(3)center dot 2H(2)O (Ln = Eu, Gd, Dy, Er, Tm, Yb)

Douglas P; Hector AL; Levason W; Light ME; Matthews ML; Webster M

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Hydrothermal synthesis of rare earth iodates from the corresponding periodates: II. Synthesis and structures of Ln(IO3)(3) (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO3)(3)center dot 2H(2)O (Ln = Eu, Gd, Dy, Er, Tm, Yb)

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Hydrothermal synthesis of rare earth iodates from the corresponding periodates: II. Synthesis and structures of Ln(IO3)(3) (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO3)(3)center dot 2H(2)O (Ln = Eu, Gd, Dy, Er, Tm, Yb)

机译：由相应的高碘酸盐水热合成稀土碘酸盐：II。 Ln（IO3）（3）（Ln = Pr，Nd，Sm，Eu，Gd，Tb，Ho，Er）和Ln（IO3）（3）中心点2H（2）O（Ln = Eu， Gd，Dy，Er，Tm，Yb）

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Single crystals of lanthanide iodates have been quickly grown by decomposition of the corresponding periodates under hydrothermal conditions. Single crystal X-ray diffraction showed that two structure types form with the elements from Pr-Yb, an anhydrous form for Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er and a dihydrate for Eu, Gd, Dy, Er, Tm, Yb. A detailed structure study is presented for one representative of each of these types, along with structure type and lattice parameters for the other materials.Tb(IO3)(3): Space group P2(1)/c, Z = 4, lattice dimensions at 120 K: a = 7.102(1), b = 8.468(1), c = 13.355(2) Angstrom, beta = 99.67(1)degrees; R1 = 0.034.Yb(IO3)(3) . 2H(2)O: Space group P (1) over bar, Z = 2, lattice dimensions at 120 K: a = 7.013(1), b = 7.370(1), c = 10.458(2) Angstrom, alpha = 95.250(5), beta = 105.096(5), gamma = 109.910(10)degrees; R1 = 0.024.

机译：通过在水热条件下分解相应的高碘酸盐，碘化镧系元素单晶已迅速生长。 X射线单晶衍射表明，Pr-Yb元素具有两种结构类型，Pr，Nd，Sm，Eu，Gd，Tb，Ho，Er为无水形式，Eu，Gd，Dy，Er为二水合物。，Tm，Yb。针对每种类型的代表进行了详细的结构研究，以及其他材料的结构类型和晶格参数.Tb（IO3）（3）：空间群P2（1）/ c，Z = 4，晶格尺寸在120 K时：a = 7.102（1），b = 8.468（1），c = 13.355（2）埃，β= 99.67（1）度; R1 = 0.034.Yb（IO3）（3）。 2H（2）O：条形上的空间组P（1），Z = 2，120 K时的晶格尺寸：a = 7.013（1），b = 7.370（1），c = 10.458（2）埃，alpha = 95.250 （5），β= 105.096（5），伽马= 109.910（10）度; R1 = 0.024。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2004年第3期|共5页
作者
Douglas P; Hector AL; Levason W; Light ME; Matthews ML; Webster M;
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正文语种 eng
中图分类化学;
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hydrothermal; iodate; lanthanide; terbium; ytterbium; crystal structure; TRANSITION-METAL IODATES; CRYSTAL-STRUCTURE; LANTHANIDE IODATES; NLO PROPERTIES; RB; CS;

机译：热液;碘酸盐;镧系元素;ter;y;晶体结构;过渡金属碘酸盐;晶体结构;镧系碘酸盐;NLO性质;RB;CS;

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1. Hydrothermal synthesis of rare earth iodates from the corresponding periodates: II. Synthesis and structures of Ln(IO3)(3) (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO3)(3)center dot 2H(2)O (Ln = Eu, Gd, Dy, Er, Tm, Yb) [J] . Douglas P, Hector AL, Levason W, Zeitschrift fur Anorganische und Allgemeine Chemie . 2004,第3期

机译：由相应的高碘酸盐水热合成稀土碘酸盐：II。 Ln（IO3）（3）（Ln = Pr，Nd，Sm，Eu，Gd，Tb，Ho，Er）和Ln（IO3）（3）中心点2H（2）O（Ln = Eu， Gd，Dy，Er，Tm，Yb）
2. Syntheses and crystal structures of rare earth basic nitrates hydrates Part III. [Ln_6(mu_6-O)(mu_3-OH)_8(H_2O)_(12)(eta~2-NO_3)_6](NO_3)_2 centre dot xH_2O, Ln = Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu; x = 3,4,5, 6 [J] . Gerald Giester, Zdirad Zak, Peter Unfried Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2009,第1a2期

机译：稀土碱式硝酸盐的合成和晶体结构水合第三部分。 [Ln_6（mu_6-O）（mu_3-OH）_8（H_2O）_（12）（eta〜2-NO_3）_6]（NO_3）_2中心点xH_2O，Ln = Y，Sm，Eu，Gd，Tb，Dy ，Ho，Er，Tm，Yb，Lu; x = 3,4,5，6
3. Facile synthesis and multicolor luminescence properties of Gd_4O_3F_6:Ln~(3+) (Ln = Eu, Tb, Dy, Sm, Ho, Tm, Yb/Er, Yb/Ho) microcrystals [J] . Liu Wei, Li Yi, Song Yanhua, Optical Materials . 2019,第Auga期

机译：Gd_4O_3F_6：Ln〜（3+）（Ln = Eu，Tb，Dy，Sm，Ho，Tm，Yb / Er，Yb / Ho）微晶的简便合成和多色发光性质
4. Dielectric properties of nano crystalline LnTiNbO6 (Ln = Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb) ceramics [C] . Fergy John, J.K. Thomas, Sam Solomon International Conference on Materials Science and Technology . 2015

机译：纳米晶体Lntinbo6（Ln = Ce，Pr，Nd，Sm，Gd，Dy，Er，Yb）陶瓷的介电性能
5. Experimental and thermodynamic investigation of RE-Mg-Zn (RE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) systems [D] . Zhu, Zhijun. 2015

机译：RE-Mg-Zn（RE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu）系统的实验和热力学研究
6. Heterometallic Octanuclear NiII4LnIII4 (Ln = Y Gd Tb Dy Ho Er) ComplexesContaining NiII2LnIII2O4 Distorted Cubane Motifs: Synthesis Structure andMagnetic Properties [O] . Pankaj Kalita, Joydeb Goura, Juan Manuel Herrera, 2018

机译：杂金属八核NiII4LnIII4（Ln = YGdTbDyHoEr）配合物包含NiII2LnIII2O4扭曲的古巴图案：合成结构和磁性能
7. Correction: Up/down conversion luminescence properties of (Na0.5Gd0.5)MoO4:Ln3+ (Ln = Eu, Tb, Dy, Yb/Er, Yb/Tm, and Yb/Ho) microstructures: synthesis, morphology, structural and magnetic investigation [O] . Rajagopalan Krishnan, Jagannathan Thirumalai 2015

机译：校正：上/下转换发光性（Na0.5GD0.5）MOO4：LN3 +（LN = EU，TB，DY，YB / ER，YB / TM和YB / HO）的微观结构：合成，形态，结构和磁性调查

Hydrothermal synthesis of rare earth iodates from the corresponding periodates: II. Synthesis and structures of Ln(IO3)(3) (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er) and Ln(IO3)(3)center dot 2H(2)O (Ln = Eu, Gd, Dy, Er, Tm, Yb)

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