A bicapped alpha-keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)[Mo8V7O42{Cu(en)(2)}]

Zeng QX; Xu JQ; Song YJ; Cui XB; Shi Z

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >A bicapped alpha-keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)[Mo8V7O42{Cu(en)(2)}]

【24h】

A bicapped alpha-keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)[Mo8V7O42{Cu(en)(2)}]

机译：双峰的α-角蛋白单元支撑的过渡金属配合物：[Cu（en）（2）（H2O）]（2）[Cu（en）（2）]（0.5）[Mo8V7O42 {Cu（en ）（2）}]

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new metal-oxo cluster supported transition metal complex, [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)((Mo8V6VO42)-V-VI-V-IV-O-V{Cu(en)(2)}] has been synthesized under hydrothermal conditions. Its structure was determined by single-crystal X-ray diffraction. The compound crystallizes in the triclinic system, space group P (1) over bar (No. 2). a = 12.245(5), b = 12.669(5), c = 20.949(8) angstrom, alpha = 77.120(13), beta = 78.107(17), gamma = 65.560(14)degrees, V = 2860(2) angstrom Z = 2. The metal-oxo cluster contains it novel bicapped a-Keggin structure unit and a [Cu(en)(2)](2+) unit covalently bonded to the [Mo8V7,O-42](7-) cluster.

机译：一种新的金属-氧簇簇过渡金属配合物[Cu（en）（2）（H2O）]（2）[Cu（en）（2）]（0.5）（（Mo8V6VO42）-V-VI-V-IV -OV {Cu（en）（2）}]是在水热条件下合成的，其结构是通过单晶X射线衍射确定的。该化合物在三斜晶系中结晶，空间群P（1）超过bar（No 。2）。a = 12.245（5），b = 12.669（5），c = 20.949（8）埃，alpha = 77.120（13），beta = 78.107（17），伽马= 65.560（14）度，V = 2860（2）埃Z =2。金属氧簇包含新的二等分a-Keggin结构单元和与[Mo8V7，O-42]共价结合的[Cu（en）（2）]（2+）单元。（7-）群集。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2005年第8期|共4页
作者
Zeng QX; Xu JQ; Song YJ; Cui XB; Shi Z;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
metal-oxo cluster; bicapped alpha-keggin structure; hydrothermal synthesis; crystal elucidation; OXIDE CHAINS; CLUSTERS; CHEMISTRY; SOLIDS;

机译：金属-氧代簇;二阶α-角蛋白结构;水热合成;晶体阐明;氧化物链;簇;化学性质;固体;

相似文献

外文文献
中文文献
专利

1. A bicapped alpha-keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)[Mo8V7O42{Cu(en)(2)}] [J] . Zeng QX, Xu JQ, Song YJ, Zeitschrift fur Anorganische und Allgemeine Chemie . 2005,第8期

机译：双峰的α-角蛋白单元支撑的过渡金属配合物：[Cu（en）（2）（H2O）]（2）[Cu（en）（2）]（0.5）[Mo8V7O42 {Cu（en ）（2）}]
2. First transition metal coordination compound supported on metal-oxygen cluster with bicapped quasi-Keggin structure:[Cu(en)_2(H_2O)]_4[Cu(en)_2]_(3.5) [PMo_8~(VI)V_6~(IV)O_(42)Cu(en)(1,10'-phen)]_3(centre dot)14H_2O [J] . ching-Ling Pan, Ji-Qing Xu, Yan Sun, Inorganic Chemistry Communications . 2003,第3期

机译：第一类过渡金属配位化合物负载在具有二重拟准Keggin结构的金属-氧簇上：[Cu（en）_2（H_2O）] _ 4 [Cu（en）_2] _（3.5）[PMo_8〜（VI）V_6〜（IV））O_（42）Cu（en）（1,10'-phen）] _ 3（中心点）14H_2O
3. Hydrothermal Synthesis and Crystal Structure of One Rare Earth Substituted Keggin-Type Germanotungstate [Cu(en)(2)](2)[Cu(en)(2)(H2O)](2)H-3{[Cu(en)(2)](2)[Na-2(H2O)(1.75)][K(H2O)(3)][Dy-2(H2O)(2) (GeW11O39)(3)]} center dot 6H(2)O [J] . Wang JP, Yan QX, Du XD, Journal of cluster science . 2008,第3期

机译：一种稀土取代的Keggin型锗钨酸盐[Cu（en）（2）]（2）[Cu（en）（2）（H2O）]（2）H-3 {[Cu（en）（2）]（2）[Na-2（H2O）（1.75）] [K（H2O）（3）] [Dy-2（H2O）（2）（GeW11O39）（3）]}中心点6H（2 O
4. Material removal rate during powder metallurgy Cu-Ti electrodes in electrical discharge machining of EN9 steel [C] . Abhinav Shard, Deepshikha, Vishal Gupta, International Conference on Condensed Matter and Applied Physics . 2020

机译：EN9钢电放电加工粉末冶金Cu-Ti电极的材料去除率
5. Synthesis and Characterization of Cu-Based Multinary Metal Oxides for Photoelectrochemical Water Splitting =Synthese und Charakterisierung von multin?ren Metalloxiden auf Cu-Basis für die photoelektrochemische Wasserspaltung [D] . Song, Angang. 2020

机译：用于光电化学水分解的Cu基多元金属氧化物的合成与表征=光电化学水分裂Cu基金属氧化物的合成与表征
6. Cyclometalated Ir(III) Complex as a Metalloligandand a Selective Cu(II) Sensor: Synthesis and Structural Characterizationof a Heterometallic Tetranuclear Ir(III)/Cu(II) Complex [O] . Vadapalli Chandrasekhar, *, Bani Mahanti, 2018

机译：金属配体的环金属化Ir（III）配合物和选择性Cu（II）传感器：合成与结构表征金属四核Ir（III）/ Cu（II）配合物的合成
7. Synthesis and Structure of Cu(Hapn)NO3NO3, Cu(Hapn)(H2O)2SiF6, Cu(Hapn)(H2O)BF4BF4∙H2O and Cu(Hapn)(NH2SO3)2 π-complexes (apn = 3-(prop-2-en-1-ylamino)propanenitrile) [O] . Mykhailo Lukyanov, Evgeny Goreshnik, Vasyl Kinzhybalo, 2017

机译：T（HAPN）NO3 H2O）BF4（H2O）（H2O）（H2O2）π-胞嘧啶的合成及结构（APR = 3-（PROP-2-8-1-1-1- ylamino）丙二醛）

A bicapped alpha-keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)(2)(H2O)](2)[Cu(en)(2)](0.5)[Mo8V7O42{Cu(en)(2)}]

摘要

著录项

相似文献

相关主题

期刊订阅