Crystal structure of the new cobalt tellurite chloride Co5Te4O11Cl4

Becker R; Johnsson M; Berger H

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Crystal structure of the new cobalt tellurite chloride Co5Te4O11Cl4

机译：新型氯化亚碲钴Co5Te4O11Cl4的晶体结构

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The crystal structure of the new compound Co5Te4O11Cl4 is described. It crystallizes in the triclinic system, space group P-1 with the unit cell parameters a = 822.26(8) pm, b = 1029.7(1) pm, c = 1031.1(1) pm, alpha = 110.80(1)degrees, beta = 97.950(9)degrees, gamma = 98.260(9)degrees and Z = 2. The structure is layered along the bc-plane and built by [CoO5Cl], [CoO4Cl2] and [CoO4Cl] polyhedra sandwiched by [TeO3E] and [TeO4E] polyhedra. The layers can be regarded as infinite molecules without any net charge and only weak van der Waals forces connect them to each other. The halides and the lone-pair, E, of Te-IV protrude from the layers.

机译：描述了新化合物Co5Te4O11Cl4的晶体结构。它在三斜晶系系统P-1中结晶，其晶胞参数a = 822.26（8）pm，b = 1029.7（1）pm，c = 1031.1（1）pm，alpha = 110.80（1）degrees，beta = 97.950（9）度，γ= 98.260（9）度，Z =2。该结构沿bc平面分层，并由[CoO5Cl]，[CoO4Cl2]和[CoO4Cl]多面体夹在[TeO3E]和[ TeO4E]多面体。这些层可以看作是无限分子，没有任何净电荷，只有弱的范德华力将它们彼此连接。 Te-IV的卤化物和孤对E从层中突出。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2007年第3期|共3页
作者
Becker R; Johnsson M; Berger H;
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正文语种 eng
中图分类化学;
关键词
oxohalides; tellurites; lone-pair elements; crystal structure; BOND-VALENCE PARAMETERS; MAGNETIC-PROPERTIES;

机译：含氧卤化物;碲酸盐;孤对元素;晶体结构;键价参数;磁性能;

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Crystal structure of the new cobalt tellurite chloride Co5Te4O11Cl4

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