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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis, crystal structure, and emission spectra of lanthanum(III) coordination polymer with 1,5-naphthalenedisulfonate ligand
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Synthesis, crystal structure, and emission spectra of lanthanum(III) coordination polymer with 1,5-naphthalenedisulfonate ligand

机译:1,5-萘二磺酸盐配体的镧(III)配位聚合物的合成,晶体结构和发射光谱

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摘要

The first two-dimensional lanthanum(III) coordination polymer, [La(1,5-NDS)(1.5)(H2O)(5)]n (1) (1,5-NDS2- = 1,5-naphthalenedisulfonate), was synthesized and structurally characterized by single-crystal X-ray diffraction analysis. The disulfonate ligands act in the eta(1):eta(1):mu(2) and eta(1):eta(1):eta(1):mu(3) and binding modes to link the LaO9 tricapped trigonal prisms into a lamellar structure. It exhibits strong purple emission in the solid state.
机译:第一个二维镧(III)配位聚合物[La(1,5-NDS)(1.5)(H2O)(5)] n(1)(1,5-NDS2- = 1,5-萘二磺酸盐),合成并通过单晶X射线衍射分析对其结构进行表征。二磺酸盐配体在eta(1):eta(1):mu(2)和eta(1):eta(1):eta(1):mu(3)中起作用,并以结合模式连接LaO9三棱柱变成层状结构。它在固态时表现出强烈的紫色发射。

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