Bis[(mu-iodo)iodo-eta-cyclopentadienylruthenium(III)], 'CpRuI2' = [CpRuI2](2): a Further Example of a [CpXM(mu-X)(2)MXCp] parent with cis arrangement

Bruce MI; Jevric M; Skelton BW; White AH

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Bis[(mu-iodo)iodo-eta-cyclopentadienylruthenium(III)], 'CpRuI2' = [CpRuI2](2): a Further Example of a [CpXM(mu-X)(2)MXCp] parent with cis arrangement

机译：Bis [（mu-iodo）iodo-eta-cyclopentadienyl钌（III）]，'CpRuI2'= [CpRuI2]（2）：具有顺式排列的[CpXM（mu-X）（2）MXCp]母体的另一个例子

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The very limited array of (structurally described) adducts of the form [CpMX2](2) [CpMX(mu-X)(2)MXCp] with the unsubstituted/parent Cp ( C5H5, cyclopentadienyl) ligand is augmented by a study of [CpIRu(mu-I)(2)RuICp], found to be isotypic with the recently described chloride and, with it, providing the only examples of such dimers in their 'cis' form, i.e., the terminal-X and Cp pairs to the same side of the Ru-2(mu-X)(2) arrays, which are appreciably folded at the X center dot center dot center dot X lines, with the short Ru center dot center dot center dot Ru distances (2.7748(6) (X = Cl), 2.9034(8) angstrom (X = 1)), consistent with the presence of appreciable metal-metal bonding (cf the M = Cr, X = Cl counterpart which is trans, Cr center dot center dot center dot Cr 3.3447(8) angstrom).

机译：[CpMX2]（2）[CpMX（mu-X）（2）MXCp]形式与未取代/母体Cp（C5H5，环戊二烯基）配体的非常有限的（结构描述）加合物阵列通过[ CpIRu（mu-I）（2）RuICp]，发现与最近描述的氯化物是同型的，并提供了这种二聚体“顺式”形式的唯一实例，即，末端的X和Cp对Ru-2（mu-X）（2）阵列的同一侧，在X中心点中心点中心点X线处明显折叠，Ru中心点中心点中心点Ru的距离短（2.7748（6 ）（X = Cl），2.9034（8）埃（X = 1）），与存在明显的金属-金属键合（cf M = Cr，X = Cl对应物为反式，Cr中心点中心点中心）一致点Cr 3.3447（8）埃）。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2008年第7期|共4页
作者
Bruce MI; Jevric M; Skelton BW; White AH;
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正文语种 eng
中图分类化学;
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ruthenium; halides; iodine; binuclear complexes; metal-metal bond; crystal structure; DEMANDING CYCLOPENTADIENYL LIGANDS; HALF-SANDWICH COMPLEXES; (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM COMPLEXES; DIMERIC (PENTAMETHYLCYCLOPENTADIENYL)RHODIUM; SERIES; SUBSTITUENTS; SYSTEMATICS; CHEMISTRY;

机译：钌;卤化物;碘;双核络合物;金属-金属键;晶体结构;要求的环戊二烯配体;半-三元络合物;（戊基环戊二烯基）铱络合物;二聚（戊基环戊二烯基）铑;系列;

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1. Bis[(mu-iodo)iodo-eta-cyclopentadienylruthenium(III)], 'CpRuI2' = [CpRuI2](2): a Further Example of a [CpXM(mu-X)(2)MXCp] parent with cis arrangement [J] . Bruce MI, Jevric M, Skelton BW, Zeitschrift fur Anorganische und Allgemeine Chemie . 2008,第6a7期

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Bis[(mu-iodo)iodo-eta-cyclopentadienylruthenium(III)], 'CpRuI2' = [CpRuI2](2): a Further Example of a [CpXM(mu-X)(2)MXCp] parent with cis arrangement

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