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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >THE REACTION OF P3N3CL4(NH2)(2) WITH HCL - THE CRYSTAL STRUCTURE OF P3N3CL5(NH2)
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THE REACTION OF P3N3CL4(NH2)(2) WITH HCL - THE CRYSTAL STRUCTURE OF P3N3CL5(NH2)

机译:P3N3CL4(NH2)(2)与HCl的反应-P3N3CL5(NH2)的晶体结构

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摘要

P3N3Cl5(NH2) in high purity and a good yield can be obtained by the reaction of P3N3Cl4(NH2)(2) With gaseous HCl in acetonitrile. If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)(2)]Cl-+(-) is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2) was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2) and [P3N3Cl4H(NH2)(2)]Cl-+(-) are also briefly discussed. [References: 34]
机译:通过使P3N3Cl4(NH2)(2)与气态HCl在乙腈中反应,可以获得高纯度和高收率的P3N3Cl5(NH2)。如果使用乙醚或二氯甲烷作为溶剂,则会形成盐状化合物[P3N3Cl4H(NH2)(2)] Cl-+(-)代替P3N3Cl5(NH2)作为微晶产物。通过X射线结构分析确定P3N3Cl5(NH2)的晶体结构。还简要讨论了P3N3Cl5(NH2)和[P3N3Cl4H(NH2)(2)] Cl-+(-)的振动光谱和热学行为。 [参考:34]

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