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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >TERNARY HALIDES OF THE A(3)MX(6)TYPE .7. THE BROMIDES LI3MBR6 (M = SM-LU, Y) - SYNTHESIS, CRYSTAL STRUCTURE, AND IONIC MOBILITY [German]
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TERNARY HALIDES OF THE A(3)MX(6)TYPE .7. THE BROMIDES LI3MBR6 (M = SM-LU, Y) - SYNTHESIS, CRYSTAL STRUCTURE, AND IONIC MOBILITY [German]

机译:A(3)MX(6)类型的三元卤化物.7。溴化物LI3MBR6(M = SM-LU,Y)-合成,晶体结构和离子淌度[德语]

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The bromides Li3MBr6 (M=Sm-Lu, Y) are obtained from the binary components LiBr and MBr3. They crystallize with a substitution/addition variant of the AlCl3-type of structure as was established from single crystal X-ray diffraction data for Li3ErBr6 (monoclinic, C2/m, Z=2, a=689.0(3), b=1191.6(9), c=684.2(6)pm, beta=109.77(6)degrees) and by powder X-ray diffraction for the remaining bromides. They are isotypic with Na3GdI6 and Li3ScCl6, respectively. Impedance spectroscopy and Li-7-NMR spectroscopy show that the lithium ions are highly mobile. [References: 19]
机译:溴化物Li3MBr6(M = Sm-Lu,Y)由二元组分LiBr和MBr3获得。如根据Li3ErBr6的单晶X射线衍射数据所确定的,它们具有AlCl3型结构的取代/加成变体结晶(单斜晶,C2 / m,Z = 2,a = 689.0(3),b = 1191.6( 9),c = 684.2(6)pm,β= 109.77(6)度),并且通过粉末X射线衍射分析剩余的溴化物。它们分别与Na3GdI6和Li3ScCl6同型。阻抗谱和Li-7-NMR谱表明锂离子具有很高的移动性。 [参考:19]

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