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首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >RHTECL - THE FIRST CHALCOGENIDE HALIDE OF A PLATINUM METAL WITH LAYER STRUCTURE [German]
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RHTECL - THE FIRST CHALCOGENIDE HALIDE OF A PLATINUM METAL WITH LAYER STRUCTURE [German]

机译:RHTECL-具有层状结构的铂金属的第一硫属元素卤化物[德国]

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摘要

Black, platelet like crystals of RhTeCl were obtained by chemical transport reaction. The crystal structure of this new chalkogenide halide of a platinum metal was determined at room temperature by single crystal X-ray diffrac tion on an ''Imaging-Plate''-diffractometer. Ln contradiction to other known chalkogenide halides of platinum metals RhTeCl crystallizes in a layer structure which is derivable from the CdI2-structure type and which can be refined in the monoclinic spacegroup Cm with the lattice constants a = 1298.81(24), b = 364.05(4), c = 665.28(13) pm, beta = 118.76(2)degrees. [References: 12]
机译:通过化学转运反应获得RhTeCl的黑色,片状晶体。在室温下通过“成像板”衍射仪上的单晶X射线衍射测定这种新的铂金属的卤化铂卤化物的晶体结构。与其他已知的铂族金属卤化卤化物Ln相矛盾的是RhTeCl结晶成层结构,该层结构可衍生自CdI2结构类型,并可在单斜空间群Cm中以晶格常数a = 1298.81(24),b = 364.05( 4),c = 665.28(13)pm,β= 118.76(2)度。 [参考:12]

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