Another example for the ability of the SbS33- anion to act as a bidentate ligand: Solvothermal synthesis, crystal structure, calculated and experimental Raman spectra of [Cr(tren)SbS3]center dot H2O

Moler K; Nather C; Bannwarth A; Bensch W

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Another example for the ability of the SbS33- anion to act as a bidentate ligand: Solvothermal synthesis, crystal structure, calculated and experimental Raman spectra of [Cr(tren)SbS3]center dot H2O

机译：SbS33-阴离子充当二齿配体的能力的另一个例子：溶剂热合成，晶体结构，[Cr（tren）SbS3]中心点H2O的计算和实验拉曼光谱

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The new charge neutral complex [Cr(tren)SbS3] center dot H2O was synthesized under solvothermal conditions applying CrCl3 center dot 6H(2)O, Sb2S3, and S as starting material in an aqueous tren solution (tren = tris(2-aminoethyl)amine)). The compound crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1), with a = 8.7779(15), b = 10.7122(17), c = 15.4286(18) angstrom, V = 1450.8(4) angstrom(3). In the structure the Cr3+ ion is surrounded by four N atoms of the amine molecules and by two S atoms of a trigonal pyramidal [SbS3](3-) group, i.e., the latter acts as a bidentate ligand. A three-dimensional network is formed via hydrogen bonds between the complexes and water molecules. The main resonances in the Raman spectrum can be explained on the basis of calculated data. The most intense band is due to the Sb-S stretching vibration. The thermal properties were investigated by DTA-TG measurements. On heating [Cr(tren)SbS3] center dot H2O decomposes in two distinct steps. The first step corresponds to the removal of the water molecules and the second step to the loss of the tren ligand.

机译：在溶剂热条件下，以CrCl3中心点6H（2）O，Sb2S3和S为起始原料，在水溶液中合成了新的电荷中性配合物[Cr（tren）SbS3]中心点H2O（tren =三（2-氨基乙基））胺））。该化合物在非中心对称空间群P2（1）2（1）2（1）中结晶，a = 8.7779（15），b = 10.7122（17），c = 15.4286（18）埃，V = 1450.8（ 4）埃（3）。在该结构中，Cr 3+离子被胺分子的四个N原子和一个三角锥体[SbS3]（3-）基团的两个S原子包围，即后者充当二齿配体。通过络合物和水分子之间的氢键形成三维网络。拉曼光谱中的主要共振可以基于计算的数据来解释。最强的带是由于Sb-S拉伸振动。通过DTA-TG测量研究热性能。加热[Cr（tren）SbS3]时，中心点H2O在两个不同的步骤中分解。第一步对应于水分子的去除，第二步对应于tren配体的损失。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2007年第15期|共6页
作者
Moler K; Nather C; Bannwarth A; Bensch W;
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中图分类化学;
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thioantimonate; crystal structure; Raman spectra; thermochemistry; HYDROTHERMAL SYNTHESIS; THERMAL-STABILITY; TRANSITION-METAL; LAYERED THIOANTIMONATE(III); ANTIMONY SULFIDE; 1ST EXAMPLE; MN-2(L)SB2S5 FAMILY; MAGNETIC-PROPERTIES; STRUCTURE DIRECTOR; BUILDING UNITS;

机译：硫代锑酸盐;晶体结构;拉曼光谱;热化学;水热合成;热稳定性;过渡金属;层状硫锑酸盐（III）;锑硫化物;第一个实例;MN-2（L）SB2S5家族;磁性体;结构方向;单位;

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1. Another example for the ability of the SbS33- anion to act as a bidentate ligand: Solvothermal synthesis, crystal structure, calculated and experimental Raman spectra of [Cr(tren)SbS3]center dot H2O [J] . Moler K, Nather C, Bannwarth A, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第15期

机译：SbS33-阴离子充当二齿配体的能力的另一个例子：溶剂热合成，晶体结构，[Cr（tren）SbS3]中心点H2O的计算和实验拉曼光谱
2. Solvothermal synthesis, crystal structures, and properties of new selenidoantimonates [Ln(en)(4)(SbSe4)] (Ln = La, Nd) and [Sm(en)(4)]SbSe4 center dot 0.5en: The first example of an SbSe43- anion acting as a ligand to a lanthanide complex [J] . Jia DM, Zhao QX, Zhang Y, European journal of inorganic chemistry . 2006,第14期

机译：溶剂热合成，晶体结构和新硒代锑酸盐[Ln（en）（4）（SbSe4）]（Ln = La，Nd）和[Sm（en）（4）] SbSe4中心点0.5en的性质： SbSe43-阴离子充当镧系元素络合物的配体
3. Solvothermal synthesis and crystal structures of two Thioantimonate(V) compounds with the [SbS4](3-) anion acting as a monodentate ligand: [Mn(C6H18N4)(C6H19N4)]SbS4 and [Mn(C6H14N2)(3)](2)[Mn(C6H14N2)(2)(SbS4)(2)]center dot 6H(2)O [J] . Schaefer M., Engelke L., Bensch W. Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第11期

机译：[SbS4]（3-）阴离子作为单齿配体的两种硫代锑酸盐（V）化合物的溶剂热合成和晶体结构：[Mn（C6H18N4）（C6H19N4）] SbS4和[Mn（C6H14N2）（3）]（2 ）[Mn（C6H14N2）（2）（SbS4）（2）]中心点6H（2）O
4. Synthesis and Crystal Structure of 3-D Complex Cr(phen)(C2O4)3Mn(phen)2(H2O)22ClO4·14H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：3-D络合物Cr（phen）（C2O4） 3 Mn（phen）2（H2O）2 2ClO4·14H2O的合成及晶体结构
5. EPR studies of oxo-molybdemun(V) complexes with sulfur donor ligands: Synthesis, X-band EPR spectra and approaches to single crystal host lattices [D] . Dhawan, Ish Kumar 1995

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机译：包含两个具有不同配体环境的镍（II）配合物的镍化合物的晶体结构：Ni（tren）（H2O）2 Ni（H2O）6（SO4）2
7. The effect of temperature onto the crystal structure of thioantimonates: solvothermal syntheses and crystal structures of [Co(dien)2][Co(tren)SbS4]20.5 H2O and {[Co(tren)]2[CoSb2S6]}H2O [O] . Bensch, Wolfgang, Lichte, Jessica, Lühmann, Henning, 2009

机译：温度对硫代锑酸盐晶体结构的影响：[Co（dien）2] [Co（tren）SbS4]20.5H2O和{[Co（tren）] 2 [CoSb2S6]}H2O的溶剂热合成和晶体结构
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机译：四甲基铵的新合成，晶体结构和振动光谱以及氟阴离子与HN3和叠氮阴离子与HF的反应

Another example for the ability of the SbS33- anion to act as a bidentate ligand: Solvothermal synthesis, crystal structure, calculated and experimental Raman spectra of [Cr(tren)SbS3]center dot H2O

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