STABILIZATION OF OXOHALOGENO AND HALOGENOCHALCOGENATES(IV) BY PROTON ACCEPTORS - SYNTHESIS, STRUCTURES AND PROPERTIES OF [C4H10NO](2)[SEOCL4], [C4H10NO](2)[SE2BR10] AND [(CH3)(2)CHC(NH2)(OH)][TE3CL13]CENTER-DOT(CH3)(2)CHCN [German]

Hasche S.; Beckmann I.; Krebs B.; Reich O.

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STABILIZATION OF OXOHALOGENO AND HALOGENOCHALCOGENATES(IV) BY PROTON ACCEPTORS - SYNTHESIS, STRUCTURES AND PROPERTIES OF [C4H10NO](2)[SEOCL4], [C4H10NO](2)[SE2BR10] AND [(CH3)(2)CHC(NH2)(OH)][TE3CL13]CENTER-DOT(CH3)(2)CHCN [German]

机译：质子受体稳定氧代羰基和卤代碳酸根（IV）-[C4H10NO]（2）[SEOCL4]，[C4H10NO]（2）[SE2BR10]和[（CH3）（2）CHC（NH2） OH）] [TE3CL13] CENTER-DOT（CH3）（2）CHCN [德语]

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Pale yellow crystals of the compound [C4H10NO](2)[SeOCl4] (1) were isolated by adding morpholine to a saturated solution of SeCl4 in 98% ethanol (space group Pnma, a = 7.731(5) Angstrom, b = 21.053(16) Angstrom, c = 9.725(8) Angstrom at 150 K). The square pyramidal [SeOCl4](2-) anion in this morpholinium salt is a partial hydrolysis product of chloroselenates(IV). The anions are connected to chains by weak Se ... Cl interactions. The morpholinium cations form hydrogen bonds to Cl atoms of the anions. The red compound [C4H10NO](2)[SeBr10] (2) was synthesised by adding morpholine to a saturated solution of SeBr4 in 47% hydrobromic acid (space group P2(1)/c, a = 8.357(2) Angstrom, b = 17.656(6) Angstrom, c = 8.495(2) Angstrom, beta = 95.49(2)degrees at 150 K). The [Se2Br10](2-) anions consist of two edge sharing distorted octahedra. Intermolecular interaction connect the anions to a two-dimensional network. [References: 35]

机译：通过将吗啉加入到SeCl4在98％乙醇中的饱和溶液中，分离出化合物[C4H10NO]（2）[SeOCl4]（1）的浅黄色晶体（空间群Pnma，a = 7.731（5）埃，b = 21.053（ 16）埃，在150 K时c = 9.725（8）埃）。此吗啉盐中的方形金字塔形[SeOCl4]（2-）阴离子是氯硒酸酯（IV）的部分水解产物。阴离子通过弱的Se ... Cl相互作用连接到链上。吗啉阳离子与阴离子的Cl原子形成氢键。通过将吗啉加到SeBr4在47％氢溴酸中的饱和溶液（空间群P2（1）/ c，a = 8.357（2）埃，b）中合成红色化合物[C4H10NO]（2）[SeBr10]（2）＝ 17.656（6）埃，c = 8.495（2）埃，β= 150 K时95.49（2）度。 [Se2Br10]（2-）阴离子由两个边缘共享的扭曲八面体组成。分子间的相互作用将阴离子连接到二维网络。 [参考：35]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第5期|共11页
作者
Hasche S.; Beckmann I.; Krebs B.; Reich O.;
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中图分类化学;
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Crystal structure; Halogenochalcogenates(iv); Oxohalogeno chalcogenates(iv); Tetrachlorooxoselenate(iv); Decabromodiselenate(iv); Tridecachlorotritellurate(iv); Crystal-structures;

机译：晶体结构;卤代胆酸盐（iv）;硫代卤素卤化物（iv）;四氯氧次硒酸盐（iv）;十溴二硒酸盐（iv）;三氯三碲酸叔丁酯（iv）;晶体结构;

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1. STABILIZATION OF OXOHALOGENO AND HALOGENOCHALCOGENATES(IV) BY PROTON ACCEPTORS - SYNTHESIS, STRUCTURES AND PROPERTIES OF [C4H10NO](2)[SEOCL4], [C4H10NO](2)[SE2BR10] AND [(CH3)(2)CHC(NH2)(OH)][TE3CL13]CENTER-DOT(CH3)(2)CHCN [German] [J] . Hasche S., Beckmann I., Krebs B., Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第5期

机译：质子受体稳定氧代羰基和卤代碳酸根（IV）-[C4H10NO]（2）[SEOCL4]，[C4H10NO]（2）[SE2BR10]和[（CH3）（2）CHC（NH2） OH）] [TE3CL13] CENTER-DOT（CH3）（2）CHCN [德语]
2. Synthesis, structure and optical properties of two novel luminescent polar dysprosium metal-organic frameworks: [(CH3)(2)NH2][Dy(HCOO)(4)] and [N2H5][Dy(HCOO)(4)] [J] . Ptak Maciej, Maczka Miroslaw, Gagor Anna, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2016,第5期

机译：两种新型发光极性polar金属-有机骨架的合成，结构和光学性质：[（CH3）（2）NH2] [Dy（HCOO）（4）]和[N2H5] [Dy（HCOO）（4）]
3. Manganiophosphonium salts: Synthesis, properties and structure of complexes of the type [CpMn(CO)(NO)PPh2H]BF4 and [Cp ' Mn(CO)(NO)PPh2R]X (R = H, CH3, {CpMn(CO)(NO)}; X = BF4, PF6) [German] [J] . Rudolph S., Geicke J., Lorenz IP., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2003,第6期

机译：锰phosph盐：[CpMn（CO）（NO）PPh2H] BF4和[Cp'Mn（CO）（NO）PPh2R] X类型的配合物的合成，性质和结构（R = H，CH3，{CpMn（CO）（NO）}; X = BF4，PF6）[德语]

STABILIZATION OF OXOHALOGENO AND HALOGENOCHALCOGENATES(IV) BY PROTON ACCEPTORS - SYNTHESIS, STRUCTURES AND PROPERTIES OF [C4H10NO](2)[SEOCL4], [C4H10NO](2)[SE2BR10] AND [(CH3)(2)CHC(NH2)(OH)][TE3CL13]CENTER-DOT(CH3)(2)CHCN [German]

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