Ni-II-Cd-II heterometallic coordination compounds constructed from metal-containing N,N '-rodlike building block [Ni(4 '-(3-pyridyl)-2,2 ': 6 ',2 ''-terpyridine)(2)](2+) cation

Gou L; Xu LF; Hu HM; Wang BC; Wu QR; Chen XL; Tang ZX

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Ni-II-Cd-II heterometallic coordination compounds constructed from metal-containing N,N '-rodlike building block [Ni(4 '-(3-pyridyl)-2,2 ': 6 ',2 ''-terpyridine)(2)](2+) cation

【24h】

Ni-II-Cd-II heterometallic coordination compounds constructed from metal-containing N,N '-rodlike building block [Ni(4 '-(3-pyridyl)-2,2 ': 6 ',2 ''-terpyridine)(2)](2+) cation

机译：由含金属的N，N'-棒状结构单元[Ni（4'-（3-吡啶基）-2,2'：6'，2''-叔吡啶）构成的Ni-II-Cd-II杂金属配位化合物2）]（2+）阳离子

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Based on the use of [Ni(3-pytpy)(2)][BF4](2) (3-pytpy=4'-(3-pyridyl)-2,2':6',2"-terpyridine) (1) as expanded 3, 3'-N, N'-rodlike building blocks and Cd-II atoms as metal "nodes", two novel Ni-II-Cd-II heterometallic compounds [Ni(3-pytpy)(2)Cd2Cl6] (2) and [Ni(3-pytpty)(2)Cd(NCS-kappa N)(4)]center dot CH3OH (3) have been synthesized under different conditions. In the precursory complex 1, Ni-II atom is coordinated by the tpy domains of two 3-pytpy ligands, while the pyridyl tails remain uncoordinated. In compound 2, [Ni(3-pytpy)(2)](2+) adopting cis-conformation bridges two four-coordinated Cd-II into trinuclear structure. In compound 3, [Ni(3-pytpy)(2)](2+) adopting trans-conformation connects six-coordinated Cd-II into 1D chain and the chains were packed into double-chains through face-to-face pi-pi stacking interactions.

机译：基于[Ni（3-pytpy）（2）] [BF4]（2）的使用（3-pytpy = 4'-（3-吡啶基）-2,2'：6'，2“-叔吡啶）（ 1）作为扩展的3、3'-N，N'-棒状结构单元和作为金属“节点”的Cd-II原子，两种新颖的Ni-II-Cd-II杂金属化合物[Ni（3-pytpy）（2）Cd2Cl6 ]（2）和[Ni（3-pytpty）（2）Cd（NCS-kappa N）（4）]中心点CH3OH（3）在不同条件下合成，在前体配合物1中，Ni-II原子为在化合物2中，[Ni（3-pytpy）（2）]（2+）采用顺式构象桥连接了两个四配位的Cd-II，由两个3-pytpy配体的tpy结构域协调，而吡啶基的尾巴却保持不协调。在化合物3中，采用反式构象的[Ni（3-pytpy）（2）]（2+）将六配位的Cd-II连接成一维链，并且这些链通过面对面排列成双链面pi-pi堆叠交互。

著录项

来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2008年第7期|共6页
作者
Gou L; Xu LF; Hu HM; Wang BC; Wu QR; Chen XL; Tang ZX;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
cadmium; nickel; metalloligand; terpyridine; ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEXES; POLYMER; LIGAND; TERPYRIDINE; DESIGN; METALLOLIGAND; MOLECULES;

机译：镉;镍;金属配体;吡啶;有机骨架;磁性体;晶体结构;配合物;聚合物;配体;叔丁啶;设计;金属配体;分子;

相似文献

外文文献
中文文献
专利

1. Ni-II-Cd-II heterometallic coordination compounds constructed from metal-containing N,N '-rodlike building block [Ni(4 '-(3-pyridyl)-2,2 ': 6 ',2 ''-terpyridine)(2)](2+) cation [J] . Gou L, Xu LF, Hu HM, Zeitschrift fur Anorganische und Allgemeine Chemie . 2008,第6a7期

机译：由含金属的N，N'-棒状结构单元[Ni（4'-（3-吡啶基）-2,2'：6'，2''-叔吡啶）构成的Ni-II-Cd-II杂金属配位化合物2）]（2+）阳离子
2. The relevance of the fluorine interactions in the supramolecular structure of a complex constructed from copper(II) hexafluoroacetylacetonate and the 4'-(3-pyridyl)-2,2':6',2"-terpyridine ligand. Novel C-F/π synthons involving the π-system of the terpyridine moieties and those of the hexafluoroacetylacetonate chelate rings [J] . Juan Granifo, Dominique Toledo, Maria Teresa Garland Journal of Fluorine Chemistry . 2010,第4期

机译：由六氟乙酰丙酮化铜（II）和4'-（3-吡啶基）-2,2'：6'，2“-吡啶配体构成的配合物的超分子结构中氟相互作用的相关性。新型CF /π合成子涉及三联吡啶部分和六氟乙酰丙酮酸螯合环的π系统
3. Photoactive building blocks for coordination complexes: Gilding 2,2′:6′,2″-terpyridine [J] . Constable E.C., Housecroft C.E., Kocik M.K., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第16期

机译：配位化合物的光敏结构单元：镀金2,2'：6'，2″-吡啶
4. BelRed: Constructing GPGPU graph applications with software building blocks [C] . Shuai Che, Beckmann Bradford M., Reinhardt Steven K. IEEE Conference on High Performance Extreme Computing . 2014

机译：BelRed：使用软件构建块构建GPGPU图形应用程序
5. Investigation of mercury cyanide as a building block in the formation of supramolecular coordination compounds. [D] . Draper, Neil D. 2004

机译：研究氰化汞作为超分子配位化合物形成的基础。
6. Tetracarbonatodiruthenium Fragments and Lanthanide(III) Ions as Building Blocks to Construct 2D Coordination Polymers [O] . Daniel Gutiérrez-Martín, Miguel Cortijo, Álvaro Martín-Humanes, 2019

机译：四碳二钌钌片段和镧系元素（III）离子作为构建2D配位聚合物的基础
7. Photoactive building blocks for coordination complexes: Gilding 2,2′:6′,2″-terpyridine [O] . Constable Edwin C., Housecroft Catherine E., Kocik Marzena K., 2011

机译：用于配位络合物的光活性结构单元：镀金2,2'：6'，2“ - 吡啶

Ni-II-Cd-II heterometallic coordination compounds constructed from metal-containing N,N '-rodlike building block [Ni(4 '-(3-pyridyl)-2,2 ': 6 ',2 ''-terpyridine)(2)](2+) cation

摘要

著录项

相似文献

相关主题

期刊订阅