Synthesis and crystal structures of novel copper(I) complexes of a phosphanylborane

Schwan KC; Adolf A; Bodensteiner M; Zabel M; Scheer M

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Synthesis and crystal structures of novel copper(I) complexes of a phosphanylborane

机译：膦酰基硼烷新型铜（I）配合物的合成和晶体结构

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The novel copper iodide clusters [Cu-3(mu-I)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (2) and [Cu-4(mu-I)(2)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2 center dot NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to the influence of the monodentate phosphorus ligand. This results in copper atoms with different coordination numbers within the compound. Complex 2, the major product of the reaction, contains a distorted octahedral Cu3I3-core, in which one vertex is missing. Complex 3 was isolated as a by-product and is composed of a Cu4I4-core in a distorted octahedral coordination.

机译：新型碘化铜簇[Cu-3（mu-I）（mu（3）-I）（2）（PH2BH2中心点NMe3）（3）]（2）和[Cu-4（mu-I）（2 ）（mu（3）-I）（2）（PH2BH2中心点NMe3）（3）]通过用伯膦（H2PBH2中心点NMe3）处理CuI合成（3）。两种化合物的新颖特征（已通过X射线晶体学表征）是由于单齿磷配体的影响，碘化铜核的结构不对称。这导致化合物内的铜原子具有不同的配位数。反应的主要产物络合物2包含扭曲的八面体Cu3I3核，其中缺少一个顶点。复合物3被分离为副产物，由扭曲的八面体配位的Cu4I4核组成。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2008年第8期|共5页
作者
Schwan KC; Adolf A; Bodensteiner M; Zabel M; Scheer M;
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正文语种 eng
中图分类化学;
关键词
boron; phosphorus; copper; iodide; cluster compounds; ONE-DIMENSIONAL POLYMERS; PHOSPHORUS-BORON BONDS; MONOMERIC PHOSPHINOBORANES; CATALYZED FORMATION; PHOSPHINE-BORANES; CHEMISTRY; IODIDE; PENTAPHOSPHAFERROCENE; CLUSTERS; LIGANDS;

机译：硼;磷;铜;碘化物;团簇化合物;一维聚合物;磷-硼键;单价膦基硼烷;催化形成;膦-硼烷;化学性质;碘化物;五聚磷烯;聚簇剂;

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Synthesis and crystal structures of novel copper(I) complexes of a phosphanylborane

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