Generation and structural characterization of an [(imidazol-2-ylidene)HfCl5]-anion/imidazolium cation salt

Niehues M.; Kehr G.; Frohlich R.; Erker G.

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Generation and structural characterization of an [(imidazol-2-ylidene)HfCl5]-anion/imidazolium cation salt

机译：[（咪唑-2-亚甲基）HfCl5]-阴离子/咪唑鎓阳离子盐的产生和结构表征

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The reaction of 1,3-diisopropylimidazolium chloride (3) with benzy1potassium in d(5)-bromobenzene generates the stable carbene 1,3-diisopropylimidazol-2-ylidene that is trapped by hafnium tetrachloride. A chloride anion is subsequently added to the Hf atom of the resulting intermediate to yield the salt [(1,3-diisopropylimidazol-2-ylidene)HfCl5-][1,3-diisopropylimidazolium(+)] 6 that was characterized by an X-ray crystal structure analysis. [References: 22]

机译：1,3-二异丙基咪唑氯化物（3）与苯并钾在d（5）-溴苯中的反应生成稳定的卡宾1,3-二异丙基咪唑-2-亚烷基，其被四氯化ha捕获。随后将氯离子加到所得中间体的H原子上，得到盐[[1,3-二异丙基咪唑-2-亚基] HfCl5-] [1,3-二异丙基咪唑鎓（+）] 6，其特征在于X射线晶体结构分析。 [参考：22]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2003年第10期|共4页
作者
Niehues M.; Kehr G.; Frohlich R.; Erker G.;
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正文语种 eng
中图分类化学;
关键词
Stable carbenes; Imidazol-2-ylidene; Hafnium complex; Arduengo carbene complexes; Olefin metathesis; Ligands;

机译：稳定的卡宾;咪唑-2-亚基;H配合物;Arduengo卡宾配合物;烯烃复分解;配体;

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1. Generation and structural characterization of an [(imidazol-2-ylidene)HfCl5]-anion/imidazolium cation salt [J] . Niehues M., Kehr G., Frohlich R., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2003,第10期

机译：[（咪唑-2-亚甲基）HfCl5]-阴离子/咪唑鎓阳离子盐的产生和结构表征
2. Cluster Structure of Imidazolium Salts in Methanol Controlled by the Balance of Interactions: Cation-Anion, Cation-Solvent, and Anion-Solvent [J] . Satoshi KITAOKA, Kaoru NOBUOKA, Yuichi ISHIKAWA, Analytical Sciences . 2008,第10期

机译：咪唑鎓盐在甲醇中的簇结构受相互作用平衡控制：阳离子-阴离子，阳离子-溶剂和阴离子-溶剂
3. Sum Frequency Generation Spectroscopy of Imidazolium-Based Ionic Liquids with Cyano-Functionalized Anions at the Solid Salt-Liquid Interface [J] . Chariz Y. Penalber, Gary A. Baker, Steven Baldelli The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2013,第19期

机译：咪唑鎓离子液体在固态盐-液界面处具有氰基官能化阴离子的总和产生光谱
4. Cross-linked Anion Exchange Membranes Composed of Imidazolium Salt for Alkaline Fuel Cell [C] . Feifei Song, Shuli Chen, Ying Gao, Electrochemical synthesis of fuels 3 . 2015

机译：咪唑鎓盐组成的用于碱性燃料电池的交联阴离子交换膜
5. Annulated bis(imidazolium) salts: Synthesis, characterization, and applications [D] . Boydston, Andrew Jackson 2007

机译：环状双（咪唑鎓）盐：合成，表征和应用
6. Structural characterization of two tetrachloridozincate salts of 4-carboxy-1H-imidazol-3-ium: a salt hydrate and a co-crystal salt hydrate [O] . Sean J. Martens, David K Geiger 2017

机译：4-咔氧基-1H-咪唑-3-鎓的两种四氯锌酸盐的结构表征：盐水合物和共结晶盐水合物
7. Cluster Structure of Imidazolium Salts in Methanol Controlled by the Balance of Interactions: Cation-Anion, Cation-Solvent, and Anion-Solvent [O] . Satoshi KITAOKA, Kaoru NOBUOKA, Yuichi ISHIKAWA, 2008

机译：通过相互作用平衡控制甲醇中咪唑鎓盐的簇结构：阳离子 - 阴离子，阳离子溶剂和阴离子溶剂
8. Pairing Heterocyclic Cations with closo-Icosahedral Borane and Carborane Anions. I. Benchtop Aqueous Synthesis of Binary Triazolium and Imidazolium Salts with Limited Water Solubility (Preprint) [R] . Shackelford, S. A., Bellatire, J. L., Boatz, J. A., 2009

机译：将杂环阳离子与闭合 - 二十面体硼烷和碳硼烷阴离子配对.I。台式水合成具有有限水溶性的二元三唑盐（预印本）

Generation and structural characterization of an [(imidazol-2-ylidene)HfCl5]-anion/imidazolium cation salt

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