One more compound containing the CBN~(4-) ion - Synthesis, single-crystal structure and vibrational spectra of Ca_(15)(CBN) _6(C_2)_2F_2

Reckeweg O.; Schulz A.; Di Salvo F.J.

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >One more compound containing the CBN~(4-) ion - Synthesis, single-crystal structure and vibrational spectra of Ca_(15)(CBN) _6(C_2)_2F_2

【24h】

One more compound containing the CBN~(4-) ion - Synthesis, single-crystal structure and vibrational spectra of Ca_(15)(CBN) _6(C_2)_2F_2

机译：另一种含CBN〜（4-）离子的化合物-Ca_（15）（CBN）_6（C_2）_2F_2的合成，单晶结构和振动光谱

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Single crystals of Ca_(15)(CBN)_6(C_2) _2F_2 were obtained by the reaction of graphite, hexagonal BN and CaF_2 with an excess of distilled Ca metal in silica-jacketed Ta ampoules at 1300 K. The title compound is transparent red and crystallizes isopointal to Ca_(15)(CBN)_6(C_2)_2O adopting the cubic space group Ia3?d (no. 230, Z = 8) with the cell parameter a = 1653.6(4) pm. Its vibrational spectra are compared with IR and Raman data of similar compounds from the literature and with the newly measured Raman spectra of Ca_5(BC_2)(C_2)Cl_3 and Ca_9(BC_2)_2Cl_8.

机译：Ca_（15）（CBN）_6（C_2）_2F_2的单晶是通过石墨，六角形BN和CaF_2与过量的蒸馏过的Ca金属在1300 K的带硅套的Ta安瓿中反应得到的。标题化合物为透明红色并采用像元参数a = 1653.6（4）pm的立方空间群Ia3？d（no。230，Z = 8）结晶成Ca_（15）（CBN）_6（C_2）_2O的等位面。将其振动光谱与文献中类似化合物的IR和拉曼数据以及新测量的Ca_5（BC_2）（C_2）Cl_3和Ca_9（BC_2）_2Cl_8的拉曼光谱进行了比较。

著录项

来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2010年第12期|共7页
作者
Reckeweg O.; Schulz A.; Di Salvo F.J.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Acetylide; Calcium; Cbn~(4-) anion; Structure elucidation; Vibrational spectra;

机译：乙醛;钙;Cbn〜（4-）阴离子;结构解析;振动光谱;

相似文献

外文文献
中文文献
专利

1. One more compound containing the CBN~(4-) ion - Synthesis, single-crystal structure and vibrational spectra of Ca_(15)(CBN) _6(C_2)_2F_2 [J] . Reckeweg O., Schulz A., Di Salvo F.J. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2010,第12期

机译：另一种含CBN〜（4-）离子的化合物-Ca_（15）（CBN）_6（C_2）_2F_2的合成，单晶结构和振动光谱
2. Syntheses, single-crystal structure and vibrational spectra of Ca_(15)(CBN)_6(C_2)_2H_2 [J] . Reckeweg O., Schulz A., Di Salvo F.J. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2011,第11期

机译：Ca_（15）（CBN）_6（C_2）_2H_2的合成，单晶结构和振动光谱
3. Cs4Ge9 center dot en: A novel compound with [Ge-9](4-) clusters - Synthesis, crystal structure and vibrational spectra [J] . Carrillo-Cabrera W, Aydemir U, Somer M, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第10期

机译：Cs4Ge9中心点en：具有[Ge-9]（4-）团簇的新型化合物-合成，晶体结构和振动光谱
4. Properties and microstructure of CBN-TiN-TiB_2 composites prepared by SPS using functionally-graduated SiO_2-coated cBN powder [C] . Mettaya Kitiwan, Akihiko Bo, Jianfeng Zhang 粉体粉末冶金協会大会 . 2013

机译：用功能梯度SiO_2涂层CBN粉末通过SPS制备CBN-TIN-TIB_2复合材料的性质和微观结构
5. SYNTHESIS AND SOLUTION PHASE SECONDARY ION MASS SPECTRAL STUDIES OF ANTINEOPLASTIC 1,4-BIS(2'-CHLOROETHYL)-1,4- DIAZABICYCLO(2.2.1)HEPTANE SALTS. [D] . GIESCHEN, DONALD PAUL. 1984

机译：抗肿瘤塑料1,4-双（2'-氯乙基）-1,4-二氮杂双环（2.2.1）庚烷盐的合成和溶液相二次离子质谱研究。
6. High-Pressure Synthesisof cBN Nanoparticles withHigh-Density Nanotwin Substructures [O] . Pan Ying, Yufei Gao, Bin Zhang, 2020

机译：高压合成cBN纳米粒子与高密度纳米孪生子结构
7. Prediction of Surface Roughness from Cutting Tool Vibrations in Hard Turning of AISI D2 Steel of Different Hardness with Conventional and Wiper Geometry CBN Inserts [O] . Sarnobat SS, Raval HK 2018

机译：用常规和刮水器几何CBN插入物预测不同硬度的AISI D2钢硬盘振动的表面粗糙度
8. Synthesis, Structure and Properties of BN Nanotubes, BN/SiC and CBN/SiC Micro/Nano-Whiskers [R] . Pokropyvnyy, V. 2003

机译：BN纳米管，BN / siC和CBN / siC微/纳米晶须的合成，结构与性能

One more compound containing the CBN~(4-) ion - Synthesis, single-crystal structure and vibrational spectra of Ca_(15)(CBN) _6(C_2)_2F_2

摘要

著录项

相似文献

相关主题

期刊订阅