Organometalloidal compounds with o-phenylene substituents, part XXXI. Charge-transfer complexes of 2,3,7,8-tetrakis(methylthio)chalkogenanthrenes with 7,7,8,8-tetracyanoquinodimethane and tetracyanoethene [German]

Dotze M.; Kudnig J.; Klar G.; Czepat H.

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Organometalloidal compounds with o-phenylene substituents, part XXXI. Charge-transfer complexes of 2,3,7,8-tetrakis(methylthio)chalkogenanthrenes with 7,7,8,8-tetracyanoquinodimethane and tetracyanoethene [German]

机译：具有邻亚苯基取代基的有机金属化合物，第XXXI部分。 2,3,7,8-四（甲硫基）chalkogenanteneenes与7,7,8,8-四氰基喹二甲烷和四氰基乙烯的电荷转移络合物[德国]

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The title compounds are prepared by slow evaporation of dilute solutions of the components. 2,3,7,8-Tetrakis(methylthio)thianthrene and -selenanthrene give isostructural 2:1 complexes with 7,7,8,8-tetracyanoquinodimethane (TCNQ) built up by donor/acceptor/donor units in which the TCNQ molecule is inserted into the cavity formed by two of the folded, oppositely arranged chalcogenanthrene molecules. These units are connected to chains by S ... S contacts via the methylthio groups. From 2,3,7,8-tetrakis(methylthio)thianthrene and tetracyanoethene again a 2:1 complex is obtained, however, with a columnar structure in which two donor stacks are slightly interlinked by an acceptor stack thus forming a structure with alternating donor and acceptor molecules. The molecules are arranged in such a way that an optimum overlap of the HOMOs of the donors and the LUMOs of the accepters, all of which are of pi-type character according to MNDO calculations, is secured. [References: 38]

机译：通过缓慢蒸发组分的稀溶液来制备标题化合物。 2,3,7,8-四（甲硫基）蒽和-硒基蒽与7,7,8,8-四氰基喹二甲烷（TCNQ）形成同构2：1络合物，由TCNQ分子位于其中的供体/受体/供体单元构建插入到由两个折叠的，相对排列的硫属蒽分子形成的空腔中。这些单元通过甲硫基通过S ... S触点连接到链上。从2,3,7,8-四（甲硫基）蒽和四氰基乙烯再次获得2：1的配合物，但是具有柱状结构，其中两个施主堆叠通过受体堆叠轻微地相互连接，从而形成具有交替供体的结构和受体分子。分子以确保供体的HOMO和受体的LUMO的最佳重叠的方式排列，根据MNDO计算，所有这些均具有pi型特征。 [参考：38]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |1998年第11期|共7页
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Dotze M.; Kudnig J.; Klar G.; Czepat H.;
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2; 3; 7; 8-tetrakis(methylthio)thianthrene and -selenanthrene/7; 7; 8; 8-tetracyanoquinodimethane; 2 : 1 charge-transfer complexes; donor/acceptor/donor units; 2; 3; 7; 8-tetrakis(methylthio)thianthrene/tetracyanoethene; 2 : 1 charge-transfer complex; columnar structure; Mndo calculations; H; o hydrogen-bond; Electrical-conductivity; Dielectric-relaxation;

机译：2;3;7;8-四（甲硫基）蒽和-硒蒽/ 7;7;8;8-四氰基喹二甲烷;2：1电荷转移络合物;供体/受体/供体单元;2;3;7;8-四（甲硫基）噻吨/四氰基乙烯;2：1电荷转移络合物;柱状结构;Mndo计算;H;o氢键;电导率;介电弛豫;

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1. Organometalloidal compounds with o-phenylene substituents, part XXXI. Charge-transfer complexes of 2,3,7,8-tetrakis(methylthio)chalkogenanthrenes with 7,7,8,8-tetracyanoquinodimethane and tetracyanoethene [German] [J] . Dotze M., Kudnig J., Klar G., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 1998,第11期

机译：具有邻亚苯基取代基的有机金属化合物，第XXXI部分。 2,3,7,8-四（甲硫基）chalkogenanteneenes与7,7,8,8-四氰基喹二甲烷和四氰基乙烯的电荷转移络合物[德国]
2. Charge-Transfer Complexes between Indoline-Tricyanoquinodimethane Compounds and 7,7,8,8-Tetracyanoquinodimethane [J] . Murata T, Honda G, Chong CH, Bulletin of the Chemical Society of Japan . 2008,第11期

机译：吲哚啉-三氰基喹二甲烷化合物与7,7,8,8-四氰基喹啉二甲烷之间的电荷转移配合物
3. Organometalloidal compounds with o-phenylene substituents .29. Reaction of sulfur dichloride with 2-methoxyphenol: Isolation and characterization of 2,8-dihydroxy-3,7-dimethoxy- and 1,6-dichloro-2,7-dihydroxy-3,8-dimethoxy-thianthrene [J] . Mansel V, Marthe S, Oberjat M, Journal of Chemical Research. Synopses . 1997,第8期

机译：具有邻亚苯基取代基的有机金属化合物.29。二氯化硫与2-甲氧基苯酚的反应：2,8-二羟基-3,7-二甲氧基和1,6-二氯-2,7-二羟基-3,8-二甲氧基-蒽的分离和表征
4. Tetrathiafulvalene–7,7,8,8-tetracyanoquinodimethane and tetrathiafulvalene–2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane organic charge-transfer complexes: Reusable catalysts for electron-transfer reactions [O] . Hoshyargar Faegheh, OMullane Anthony P. 2016

机译：四硫富瓦烯–7,7,8,8-四氰基喹二甲烷和四硫富富烯–2,3,5,6-四氟-7,7,8,8-四氰基喹二甲烷有机电荷转移复合物：可重复使用的电子转移反应催化剂

Organometalloidal compounds with o-phenylene substituents, part XXXI. Charge-transfer complexes of 2,3,7,8-tetrakis(methylthio)chalkogenanthrenes with 7,7,8,8-tetracyanoquinodimethane and tetracyanoethene [German]

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