Electrochemical synthesis of a 6-coordinate cadmium(II) complex with N-methylisatin N(4)-cyclohexylthiosemicarbazone

Labisbal E.; Castineiras A.; Garcia-Vazquez JA.; Romero J.; Bain GA.; West DX.; Sousa A.

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Electrochemical synthesis of a 6-coordinate cadmium(II) complex with N-methylisatin N(4)-cyclohexylthiosemicarbazone

机译：电化学合成N-甲基靛红N（4）-环己基硫代半胱氨酸六配位的镉（II）配合物

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Cadmium metal was oxidized in the presence or N-methylisatin N(4)-cyclohexylthiosemicarbazone (HMeIs4Chex) in an acetonitrile solution, which produced a complex of the formula [Cd(MeIs4Chex)(2)]. The two MeIs4Chex ligands are at an angle close to 90 degrees from each other, and there is hydrogen bonding to two adjacent molecules by the anionic ligands remaining NH groups. The complex crystallizes in the monoclinic space group P2(1)/c with a = 11.820(4). b = 11.491(4), c = 27.834(4) Angstrom, beta = 106.82(2)degrees, V = 3618.7(17) Angstrom(3) and Z = 4. [References: 28]

机译：在乙腈溶液中或在N-甲基靛红N（4）-环己基硫代半脲（HMeIs4Chex）的存在下，氧化镉金属，可制得式[Cd（MeIs4Chex）（2）]的配合物。两个MeIs4Chex配体彼此之间的角度接近90度，并且通过剩下的NH基团的阴离子配体将氢键接到两个相邻的分子上。该复合物在单斜空间群P2（1）/ c中结晶，其a = 11.820（4）。 b = 11.491（4），c = 27.834（4）埃，β= 106.82（2）度，V = 3618.7（17）埃（3），Z =4。[参考：28]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2000年第2期|共5页
作者
Labisbal E.; Castineiras A.; Garcia-Vazquez JA.; Romero J.; Bain GA.; West DX.; Sousa A.;
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正文语种 eng
中图分类化学;
关键词
Cadmium; N-methylisatin n(4)-cyclohexylthiosemicarbazone; Electrochemical synthesis; X-ray data; Copper(ii) complexes; Thiosemicarbazones;

机译：镉;N-甲基靛素n（4）-环己基硫代氨基脲;电化学合成;X射线数据;铜（ii）配合物;硫代氨基脲;

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Electrochemical synthesis of a 6-coordinate cadmium(II) complex with N-methylisatin N(4)-cyclohexylthiosemicarbazone

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