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首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >Solvothermal synthesis of multifunctional coordination polymers
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Solvothermal synthesis of multifunctional coordination polymers

机译:溶剂热合成多功能配位聚合物

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摘要

This review focuses primarily on the past 10 years of our development of multifunctional coordination polymers with 1D, 2D and 3D structures employing low-temperature and cost-effective hydrothermal and solvothermal methods. The effects of the experimental conditions and parameters on the crystal formation and phase separation, including temperature and pressure, reaction pH, solvent and composition, are discussed. Our studies have shown that a variety of different types of network structures may be rationally designed and synthesized by deliberate selection and construction of metal building blocks and organic ligands, which lead to numerous interesting properties and multifunctionality that are promising for applications in gas storage and separation, catalysis and optical sensing.
机译:这篇综述主要集中在我们使用低温且经济高效的水热和溶剂热方法开发具有1D,2D和3D结构的多功能配位聚合物的过去十年中。讨论了实验条件和参数对晶体形成和相分离的影响,包括温度和压力,反应pH,溶剂和组成。我们的研究表明,通过有选择地选择和构造金属构件和有机配体,可以合理地设计和合成各种不同类型的网络结构,这导致许多有趣的特性和多功能性,有望在气体存储和分离中应用,催化和光学传感。

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