Formation and structural characterization of [RuCl2(CO)(2)(SPh2)(2)], [RuCl2(CO)(3)(OH2)], and [Ru(OH2)(6)][RuCl3(CO)(3)](2) center dot 2H2O

Taimisto M.; Oilunkaniemi R.; Laitinen RS.; Ahlgren M.

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >Formation and structural characterization of [RuCl2(CO)(2)(SPh2)(2)], [RuCl2(CO)(3)(OH2)], and [Ru(OH2)(6)][RuCl3(CO)(3)](2) center dot 2H2O

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Formation and structural characterization of [RuCl2(CO)(2)(SPh2)(2)], [RuCl2(CO)(3)(OH2)], and [Ru(OH2)(6)][RuCl3(CO)(3)](2) center dot 2H2O

机译：[RuCl2（CO）（2）（SPh2）（2）]，[RuCl2（CO）（3）（OH2）]和[Ru（OH2）（6）] [RuCl3（CO）（）的形成和结构表征3）]（2）中心点2H2O

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While the room temperature reaction of [RuCl2(CO)(3)](2) and Ph2S in tetrahydrofuran in air affords [RuCl2(CO)(2)(SPh2)(2)] (1) in moderate yield, that in dichloromethane results in the formation of a mixture of [RuCl2(CO)(3)(H2O)] (2) and [Ru(H2O)(6)][RuCl3(CO)(3)](2).2H(2)O (3). Very small amounts of 1 are produced only upon prolonged reflux of the reagents. All compounds were characterized by X-ray crystallography. 1 crystallizes as discrete octahedral cis(CO), cis(Cl), trans(Ph2S) complexes, which are joined into stacks by weak H...Cl hydrogen bonds. 2 is also composed of discrete octahedral complexes. Four hydrogen bonds involving aqua and chlorido ligands link two complexes into a dimer. The structure of 3 consists of octahedral hexaaquaruthenium cations and two tricarbonyl-trichloridoruthenate anions. The water of crystallization is involved in hydrogen bonding between the cations and anions resulting in the formation of a continuous three-dimensional network. [References: 12]

机译：在室温下，四氯化呋喃中的[RuCl2（CO）（3）]（2）和Ph2S在室温下进行空气反应，可得到中等产率的[RuCl2（CO）（2）（SPh2）（2）]（1），在二氯甲烷中导致形成[RuCl2（CO）（3）（H2O）]（2）和[Ru（H2O）（6）] [RuCl3（CO）（3）]（2）.2H（2）的混合物O（3）。仅在试剂长时间回流后才会产生极少量的1。所有化合物均通过X射线晶体学表征。 1结晶为离散的八面体顺式（CO），顺式（Cl），反式（Ph2S）络合物，它们通过弱的H ... Cl氢键连接成叠层。 2也由离散的八面体络合物组成。涉及水和氯配体的四个氢键将两个复合物连接成一个二聚体。 3的结构由八面体六水合钌阳离子和两个三羰基-三氯钌酸根阴离子组成。结晶水参与阳离子和阴离子之间的氢键结合，从而导致形成连续的三维网络。 [参考：12]

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2003年第10期|共6页
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Taimisto M.; Oilunkaniemi R.; Laitinen RS.; Ahlgren M.;
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正文语种 eng
中图分类化学;
关键词
Ruthenium complex; Diphenyl sulfide; Crystal structure; Crystal-structure; Complexes; Ligands;

机译：钌配合物二苯硫醚晶体结构晶体结构络合物配体;

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Formation and structural characterization of [RuCl2(CO)(2)(SPh2)(2)], [RuCl2(CO)(3)(OH2)], and [Ru(OH2)(6)][RuCl3(CO)(3)](2) center dot 2H2O

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