Hydrothermal synthesis, crystal structure and catalytic properties of a novel polyoxometalate: (C_5H_7N_2) _3(AsMo_(12)O_(40)). 2C_5H_6N _2. 1.5H_2O

Cai T.-J.; Shen X.-M.; Peng Z.-S.; Lü S.-Z.; Deng Q.

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Hydrothermal synthesis, crystal structure and catalytic properties of a novel polyoxometalate: (C_5H_7N_2) _3(AsMo_(12)O_(40)). 2C_5H_6N _2. 1.5H_2O

机译：新型多金属氧酸盐（C_5H_7N_2）_3（AsMo_（12）O_（40））的水热合成，晶体结构和催化性能。 2C_5H_6N _2。 1.5H_2O

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(C_5H_7N_2)_3(AsMo _(12)O_(40)). 2C_5H_6N_2. 1.5H_2O was hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Crystal data: monoclinic, P2_1, a = 13.310(3), b = 22.399(5), c = 19.820(4) ?, β = 99.99(3)°, V = 5819(2) ?~3, Z = 1, wR(F~2) = 0.1345. The structure consists of Keggin-type [AsMo_(12)O_(40)]~(3-) polyoxoanions. The title compound has a high catalytic activity for the oxidation of acetone tested in a continuous-flow fixed-bed micro-reactor. When the initial concentration is 5.3 g m~(-3) in air and the flow rate is 2.5 mL min~(-1), the acetone is completely eliminated at 150 °C.

机译：（C_5H_7N_2）_3（AsMo _（12）O_（40））。 2C_5H_6N_2。水热合成1.5H_2O，并通过单晶X射线衍射对其结构进行表征。晶体数据：单斜晶，P2_1 / n，a = 13.310（3），b = 22.399（5），c = 19.820（4）？，β= 99.99（3）°，V = 5819（2）？〜3，Z = 1，wR（F〜2）= 0.1345。该结构由Keggin型[AsMo_（12）O_（40）]〜（3-）多氧阴离子组成。在连续流固定床微反应器中测试，标题化合物对丙酮的氧化具有高催化活性。当空气中的初始浓度为5.3 g m〜（-3），流速为2.5 mL min〜（-1）时，在150°C时丙酮被完全清除。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2010年第9期|共5页
作者
Cai T.-J.; Shen X.-M.; Peng Z.-S.; Lü S.-Z.; Deng Q.;
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正文语种 eng
中图分类化学;
关键词
Catalytic Elimination; Crystal Structure; Hydrothermal Synthesis; Keggin Structure; Polyoxometalate;

机译：催化消除;晶体结构;水热合成;Keggin结构;多金属氧酸盐;

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1. Hydrothermal synthesis, crystal structure and catalytic properties of a novel polyoxometalate: (C_5H_7N_2) _3(AsMo_(12)O_(40)). 2C_5H_6N _2. 1.5H_2O [J] . Cai T.-J., Shen X.-M., Peng Z.-S., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2010,第9期

机译：新型多金属氧酸盐（C_5H_7N_2）_3（AsMo_（12）O_（40））的水热合成，晶体结构和催化性能。 2C_5H_6N _2。 1.5H_2O
2. Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a Keggin Polyoxometalate [Cu~I(2,2 '-biopy)_2]_3[PW~(VI)_(12)O_(40)] [J] . LAN Ting-Yan, CHEN Jian-Xin, WEI Chun-Xia, Chinese Journal of Structural Chemistry . 2006,第3期

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Hydrothermal synthesis, crystal structure and catalytic properties of a novel polyoxometalate: (C_5H_7N_2) _3(AsMo_(12)O_(40)). 2C_5H_6N _2. 1.5H_2O

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