Bis(triphenylphosphine)gold(i) perrhenate

Baer S.A.; P?thig A.; Bawaked S.M.; Schmidbaur Prof. H.; Kraus Dr. F.

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Bis(triphenylphosphine)gold(i) perrhenate

机译：双（三苯基膦）金（i）高hen酸盐

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Bis(triphenylphosphine)gold(1) perrhenate [Ph~3PAuPPh ~3]+ReO~4- has been prepared in high yield from Ph ~3PAuCl, Ph~3P and AgReO~4 in a mixed solvent. The compound is stable in air and decomposes at 235 °C. In the crystal structure, the two independent perrhenate anions are not approaching the gold centers of the two independent cations, but weak interionic interactions are entertained via π-π stacking of phenyl groups and C-H...O contacts. As three-blade chiral rotors, the Ph~3P ligands of the cations are in a staggered conformation at the gold atoms with only slightly bent P-Au-P axes. IR and NMR data show no anomalies and are close to those of alkali or onium perrhenates.

机译：在混合溶剂中，由Ph〜3PAuCl，Ph〜3P和AgReO〜4以高收率制备了双（三苯基膦）金（1）高hen酸盐[Ph〜3PAuPPh〜3] + ReO〜4-。该化合物在空气中稳定，在235°C时分解。在晶体结构中，两个独立的高hen酸盐阴离子没有接近两个独立阳离子的金中心，但是通过苯基的π-π堆积和C-H ... O接触得到弱的离子间相互作用。作为三叶片手性转子，阳离子的Ph〜3P配体在金原子上呈交错构象，只有略微弯曲的P-Au-P轴。 IR和NMR数据显示无异常，并且接近碱金属或高per酸盐。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2013年第11期|共7页
作者
Baer S.A.; P?thig A.; Bawaked S.M.; Schmidbaur Prof. H.; Kraus Dr. F.;
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正文语种 eng
中图分类化学;
关键词
Crystal structure; Gold(1); IR spectra; Phosphine; Rhenate(7);

机译：晶体结构;金（1）;红外光谱;磷化氢盐（7）;

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1. Bis(triphenylphosphine)gold(i) perrhenate [J] . Baer S.A., P?thig A., Bawaked S.M., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2013,第11期

机译：双（三苯基膦）金（i）高hen酸盐
2. Pyrazolato Ligands towards Gold(I) Derivatives with Aurophilic Interactions: X-Ray Structure of Bis[3,5-(dibutoxyphenyl)-1H-pyrazolato-#kappa#N~1]bis(triphenylphosphine)digold(Au…Au)([Au(pz~(R_2))(PPh_3)]_2; R = C_4H_9-O-C_6H_4 [J] . Paloma Ovejero, Mercedes Cano, Elena Pinilla, Helvetica chimica acta . 2002,第6期

机译：Pyrazolato配体对具有亲金相互作用的金（I）衍生物的作用：Bis [3,5-（dibutoxyphenyl）-1H-pyrazolato-＃kappa＃N〜1] bis（triphenylphosphine）digold（Au…Au）（[ Au（pz〜（R_2））（PPh_3）] _ 2; R = C_4H_9-O-C_6H_4
3. Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide [J] . Wegner GL., Schier A., Schmidbaur H., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2000,第5期

机译：双[双（三甲基甲硅烷基）氨基]锗（II）的硫化和硒化产物的晶体和分子结构。（三苯基膦）金（I）双（三甲基甲硅烷基）酰胺的晶体结构
4. Synthesis And Characterization of Nano-Sized Triphenylphosphine Capped Bis(4-Methylpiperazine-1-Carbodithioato)Zinc(Ⅱ) [C] . S. B. Kalia, M. Sharma, S.S. Kanwar, National SBIR/STTR conference;Annual nanotech conference and expo;Annual TechConnect world innovation conference expo . 2015

机译：纳米三苯基膦包覆的双（4-甲基哌嗪-1-碳二硫代）锌（Ⅱ）的合成与表征
5. Mechanistic insights on nanoparticle formation: Investigation of reaction pathways and development of controlled syntheses for triphenylphosphine-stabilized undecagold. [D] . McKenzie, Lallie Cobb. 2009

机译：纳米粒子形成的力学见解：三苯膦稳定的十一醛的反应途径的研究和受控合成的发展。
6. StructurallySimilar Triphenylphosphine-StabilizedUndecagolds Au11(PPh3)7Cl3 and Au11(PPh3)8Cl2ClExhibit Distinct Ligand Exchange Pathways with Glutathione [O] . LallieC. McKenzie, †, ‡, -1

机译：结构上稳定的类似三苯膦UndecagoldsAu11（PPh3）7Cl3和Au11（PPh3）8Cl2 Cl展示与谷胱甘肽不同的配体交换途径
7. Crystal structure of (morpholine-1-carbodithioato-κ2-S,S′)bis(triphenylphosphine-κ-P)gold(I), C41H38AuNOP2S2 [O] . Tunde L. Yusuf, Michael N. Pillay, Sizwe J. Zamisa, 2021

机译：晶体结构（吗啉-1-碳二硫代乙腈-κ2-S，S'）BIS（三苯基膦-κ-P）金（I），C41H38AUNOP2S2

Bis(triphenylphosphine)gold(i) perrhenate

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