A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties

Demir Selcuk; Cepni Hamide Merve; Holynska Malgorzata; Kavanoz Muammer

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A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties

机译：具有吡唑-3,5-二羧酸酯配体的四核铜（II）配合物：合成，表征和电化学性质

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摘要

A tetranuclear copper (II) complex with pyrazole3,5-dicarboxylate ligands (pdc(3-)), [Me2NH2](4) [Cu-4(pdc)(4)], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N-H center dot center dot center dot O hydrogen bonds. In addition, the electrochemical behavior was studied.

机译：使用溶剂热和金属氧化路线合成了具有吡唑3,5-二羧酸酯配体（pdc（3-））[Me2NH2]（4）[Cu-4（pdc）（4）]的四核铜（II）配合物，并对其进行了表征通过元素分析，红外，热重/差热分析和室温磁测量。配合物的结构通过单晶X射线衍射确定。它包含二甲基铵阳离子和含有四个Cu2 +阳离子的复合阴离子。通过N-H中心点中心点中心点O氢键来稳定晶体结构。另外，研究了电化学行为。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2016年第4期|共6页
作者
Demir Selcuk; Cepni Hamide Merve; Holynska Malgorzata; Kavanoz Muammer;
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正文语种 eng
中图分类化学;
关键词
copper; crystal structure; polynuclear; pyrazole-3; 5-dicarboxylic acid; thermal analysis;

机译：铜;晶体结构;多核;吡唑-3;5-二羧酸;热分析;

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1. A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties [J] . Demir Selcuk, Cepni Hamide Merve, Holynska Malgorzata, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2016,第4期

机译：具有吡唑-3,5-二羧酸酯配体的四核铜（II）配合物：合成，表征和电化学性质
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A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties

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