Synthesis and crystal structure of a new Cd(II) coordination polymer based on a 1,10-phenanthroline derivative

Xu Z.-L.; Ma S.; He Y.; Kong Z.-G.

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Synthesis and crystal structure of a new Cd(II) coordination polymer based on a 1,10-phenanthroline derivative

机译：基于1,10-菲咯啉衍生物的新型Cd（II）配位聚合物的合成和晶体结构

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The new coordination polymer [Cd(oct)(L)] (H2oct = octanedioic acid and L = 2-(4-fluorophenyl)-1H-imidazo-[4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C27H23CdFN4O4, monoclinic, space group C2/c, a = 21.391(4), b = 18.180(4), c = 14.031(3) ?, β = 116.50(3), V = 4883(2) ?3, Z =8. The flexible oct dianions bridge the Cd(II) cations to yield a double-chain structure. The L ligands are attached on both sides of the chains, and their π-π interactions between neighboring chains result in two-dimensional supramolecular layers.

机译：合成了新的配位聚合物[Cd（oct）（L）]（H2oct =辛二酸，L = 2-（4-氟苯基）-1H-咪唑-[4,5-f] [1,10]菲咯啉）在水热条件下，通过元素分析，红外光谱和单晶X射线衍射进行表征。晶体数据：C27H23CdFN4O4，单斜晶，C2 / c空间群，a = 21.391（4），b = 18.180（4），c = 14.031（3）β，β= 116.50（3），V = 4883（2）α3 ，Z ＝ 8。柔性八价阴离子桥接Cd（II）阳离子以产生双链结构。 L个配体连接在链的两侧，并且它们在相邻链之间的π-π相互作用导致二维超分子层。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2011年第5期|共3页
作者
Xu Z.-L.; Ma S.; He Y.; Kong Z.-G.;
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正文语种 eng
中图分类化学;
关键词
2-(4-Fluorophenyl)-1H-imidazo 4; 5-f1; 10phenanthroline; Coordination polymer; Crystal structure; Octanedioic acid;

机译：2-（4-氟苯基）-1H-咪唑并[4;5-f] [1;10]菲咯啉;配位聚合物;晶体结构;辛二酸;

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机译：基于1,10-菲咯啉衍生物的新型Cd（II）配位聚合物的合成和晶体结构
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Synthesis and crystal structure of a new Cd(II) coordination polymer based on a 1,10-phenanthroline derivative

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