Assembly of 1,2,3,4-benzenetetracarboxylic acid and zinc(II) metal centers to a chiral 3D metal-organic framework: Syntheses, structure and properties

Ji C.; Zang S.-Q.; Liu J.-Y.; Li J.-B.; Hou H.-W.

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Assembly of 1,2,3,4-benzenetetracarboxylic acid and zinc(II) metal centers to a chiral 3D metal-organic framework: Syntheses, structure and properties

机译：将1,2,3,4-苯四甲酸和锌（II）金属中心组装成手性3D金属-有机骨架：合成，结构和性能

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A new three-dimensional metal-organic framework {[Zn(mpda) 0.5(bix)](H2O)1.5 }n (1) (H 4mpda = 1,2,3,4-benzenetetracarboxylic acid, m-bix = 1,3-bis(imidazol-1-ylmethyl)-benzene) has been synthesized and characterized by single-crystal X-ray diffraction and IR spectra. In 1, homochiral helical chains are formed in the Zn-mpda layer through spontaneous resolution by mpda 4-. Such layers are further connected through the second m-bix ligand to form a 3D chiral metal-organic framework. The individual (4,4)-connected net in 1 can be specified by the Schl?fli symbol (66) 2.(64.82). Bulk material of 1 has good second-harmonic generation (SHG) activity, approximately o.4 times that of urea. In addition, a thermogravimetric analysis was carried out, and the photoluminescent behavior of the complex was also investigated.

机译：新的三维金属有机骨架{[Zn（mpda）0.5（bix）]（H2O）1.5} n（1）（H 4mpda = 1,2,3,4-苯四甲酸，m-bix = 1，已经合成了3-双（咪唑-1-基甲基）-苯并通过单晶X射线衍射和IR光谱表征。在1中，通过mpda 4-的自发拆分，在Zn-mpda层中形成了手性螺旋链。这样的层通过第二m-bix配体进一步连接以形成3D手性金属-有机骨架。单个（4,4）连接的网中1可以由Schl？fli符号（66）2（64.82）指定。 1的散装物料具有良好的二次谐波生成（SHG）活性，约为尿素的0.4倍。另外，进行了热重分析，并且还研究了配合物的光致发光行为。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2011年第5期|共5页
作者
Ji C.; Zang S.-Q.; Liu J.-Y.; Li J.-B.; Hou H.-W.;
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正文语种 eng
中图分类化学;
关键词
Helical; Homochiral; Metal-organic Framework; Photoluminescence; SHG; Topology;

机译：螺旋;手性;金属有机骨架;光致发光;SHG;拓扑;

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1. Assembly of 1,2,3,4-benzenetetracarboxylic acid and zinc(II) metal centers to a chiral 3D metal-organic framework: Syntheses, structure and properties [J] . Ji C., Zang S.-Q., Liu J.-Y., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2011,第5期

机译：将1,2,3,4-苯四甲酸和锌（II）金属中心组装成手性3D金属-有机骨架：合成，结构和性能
2. In situ hydrothermal syntheses, structures and photoluminescent properties of four novel metal-organic frameworks constructed by lanthanide (Ln=Ce(III), Pr(III), Eu(III)) and Cu(I) metals with flexible dicarboxylate acids and piperazine-based ligands [J] . Ay Burak, Karaca Serkan, Yildiz Emel, Journal of Solid State Chemistry . 2016,第Null期

机译：镧系元素（Ln = Ce（III），Pr（III），Eu（III））和Cu（I）与柔性二羧酸和哌嗪-铜构成的四种新颖的金属有机骨架的原位水热合成，结构和光致发光特性基于配体
3. Syntheses, Structures, and Properties of Two Zinc(II) Metal-Organic Frameworks based on Biphenyl-2,3,3 ',5 '-tetracarboxylic Acid and N-Donor Ancillary Ligands [J] . Li Rong-Fang, Gu Yan-Xue, Liu Xin-Fang, Zeitschrift fur Anorganische und Allgemeine Chemie . 2015,第6期

机译：基于联苯-2,3,3'，5'-四羧酸和N-供体辅助配体的两种锌（II）金属-有机骨架的合成，结构和性质
4. Synthesis, crystal structure and properties of a metal-organic framework of tetraazamacrocycle copper(II) complex with benzenetetracarboxylic acid [C] . Shingo Mizutani, Hiroshi Ohki, Atsushi Ishikawa 日本化学会春季年会講演予稿集 . 2018

机译：用苯甲酸四胱铜（II）络合物的金属 - 有机骨架的合成，晶体结构和性能
5. Design, synthesis and applications of lanthanide metal-organic frameworks based on 1,2,4,5-benzenetetracarboxylic acid. [D] . Dixon, Joseph William, III. 2015

机译：基于1,2,4,5-苯四甲酸的镧系金属有机骨架的设计，合成和应用。
6. A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ) 44-Oxybis(benzoic acid) and 22-Biphenyl: Synthesis Crystal Structure and Photoelectric Property Characterization [O] . Kai-Sheng Diao, Long Li, Yu-Qiu Ding, 2012

机译：用锰（III）44-氧代双（苯甲酸）和22-联苯构建的3-D金属有机骨架：合成晶体结构和光电性能表征
7. Puckered-Boat Conformation Hexameric Water Clusters Stabilized in a 2D Metal-Organic Framework Structure Built from Cu(II) and 1, 2, 4, 5-Benzenetetracarboxylic Acid [O] . -1

机译：褶皱艇构象六偏美水簇稳定在由Cu（II）和1,2,4,5-苯甲酸四羧酸构建的2D金属 - 有机骨架结构中

Assembly of 1,2,3,4-benzenetetracarboxylic acid and zinc(II) metal centers to a chiral 3D metal-organic framework: Syntheses, structure and properties

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