Hydrothermal synthesis, crystal structure and properties of a 1D metal-organic coordination polymer [Cd(pztmb)2(H2O) 2]n

Zhou Y.; Sun X.-M.; Zang S.-Q.; Hou H.-W.

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Hydrothermal synthesis, crystal structure and properties of a 1D metal-organic coordination polymer [Cd(pztmb)2(H2O) 2]n

机译：一维金属-有机配位聚合物[Cd（pztmb）2（H2O）2] n的水热合成，晶体结构和性能

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Hydrothermal reaction of Cd(NO3)2 · 4H 2O with a flexible asymmetrical bridging ligand, 4-(2- pyrazinylthiomethyl)benzoic acid (Hpztmb), at 120 °C yielded a novel one-dimensional Cd(II) coordination polymer [Cd(pztmb)2(H 2O)2]n (1), which has been characterized by IR spectroscopy, elemental analysis, thermogravimetry, and X-ray crystallography. The metal-organic chain of the complex is held together with its neighbors via O-H- O hydrogen bonds and face-to-face π-π interactions leading to a three-dimensional supramolecular network. Compound 1 exhibits a fluorescence emission around 396 nm.

机译：Cd（NO3）2·4H 2O与柔性不对称桥联配体4-（2-吡嗪基硫甲基）苯甲酸（Hpztmb）在120°C的水热反应产生了新型的一维Cd（II）配位聚合物[Cd（ pztmb）2（H 2O）2] n（1），已通过红外光谱，元素分析，热重分析和X射线晶体学进行了表征。配合物的金属-有机链通过O-H-O氢键和面对面的π-π相互作用与邻居保持在一起，从而形成三维超分子网络。化合物1在396nm附近表现出荧光发射。

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《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2011年第5期|共5页
作者
Zhou Y.; Sun X.-M.; Zang S.-Q.; Hou H.-W.;
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正文语种 eng
中图分类化学;
关键词
π-π; 4-(2-Pyrazinylthiomethyl)benzoic Acid; Hydrogen Bond; Interactions; Metal-organic Chain; Supramolecular Structure;

机译：π-π;4-（2-吡嗪基硫代甲基）苯甲酸;氢键;相互作用;金属有机链;超分子结构;

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1. Hydrothermal synthesis, crystal structure and properties of a 1D metal-organic coordination polymer [Cd(pztmb)2(H2O) 2]n [J] . Zhou Y., Sun X.-M., Zang S.-Q., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2011,第5期

机译：一维金属-有机配位聚合物[Cd（pztmb）2（H2O）2] n的水热合成，晶体结构和性能
2. Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of a Metal-organic Coordination Polymer with Supramolecular Structure: [Cd_2(dpphen)_2(BDC)_(0.5)Cl_3]_n [J] . LIU Bo, LI Xiu-Mei, LI Chuan-Bi, Chinese Journal of Structural Chemistry . 2007,第6期

机译：具有超分子结构的金属有机配位聚合物[Cd_2（dpphen）_2（BDC）_（0.5）Cl_3] _n的水热合成，晶体结构和光致发光性能
3. Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units [J] . Hai-Hua Li, Peng Zhang, Jia-Yi Pu, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2013,第2期

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4. A new type of coordination polymer: hydrothermal synthesis, crystal structure, and magnetic properties of (C_(10)H_8N_2)_2CuBrCu_3Br_4 [C] . Brenda R. Cabrera, Ru-Ji Wang, Jing Li, Symposium on Solid-State chemistry of inorganic materials . 1999

机译：一种新型配位聚合物：水热合成，晶体结构和（C_（10）H_8N_2）_2cubr CU_3BR_4的磁性
5. The Synthesis of New Coordination Polymer Using Crystal Engineering, Self-Assembly, and Hydrothermal Synthesis [D] . Fu, Lei 2018

机译：利用晶体工程，自组装和水热合成法合成新型配位聚合物
6. From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis Crystal Structures Inclusion and Emission Properties [O] . Victor Ch. Kravtsov, Vasile Lozovan, Nikita Siminel, 2020

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Hydrothermal synthesis, crystal structure and properties of a 1D metal-organic coordination polymer [Cd(pztmb)2(H2O) 2]n

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