Crystal structures of the gold(I) phosphinine complexes [AuCl(C _5H_2P-2,6-Me_2-4-Ph)] and [AuCl(C _5H_2P-2,4,6-Ph_3)]

Stott J.; Bruhn C.; Siemeling U.

首页> 外文期刊>Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences >Crystal structures of the gold(I) phosphinine complexes [AuCl(C _5H_2P-2,6-Me_2-4-Ph)] and [AuCl(C _5H_2P-2,4,6-Ph_3)]

【24h】

Crystal structures of the gold(I) phosphinine complexes [AuCl(C _5H_2P-2,6-Me_2-4-Ph)] and [AuCl(C _5H_2P-2,4,6-Ph_3)]

机译：金（I）膦化合物[AuCl（C _5H_2P-2,6-Me_2-4-Ph）]和[AuCl（C _5H_2P-2,4,6-Ph_3）的晶体结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The gold(I) phosphinine complexes [AuCl(C_5H_2P-2,6- Me_2-4-Ph)] and [AuCl(C_5H_2P-2,4,6-Ph _3)] were prepared and structurally characterised by single-crystal X-ray diffraction studies. In the former case, individual molecules are aggregated in the crystal as crossed dimers with an Au···Au distance of 3.60 ?, compatible with a weak aurophilic interaction. In the latter case, intermolecular Au···π interactions involving the phosphinine ring are observed with Au···C distances in the range from ca. 3.32 to 3.44 ?, which make [AuCl(C _5H_2P-2,4,6-Ph_3)] the first structurally characterised example of intermolecular Au···π interactions involving a heteroarene.

机译：制备了金（I）膦配位化合物[AuCl（C_5H_2P-2,6-Me_2-4-Ph）]和[AuCl（C_5H_2P-2,4,6-Ph _3）]，并通过单晶X-射线衍射研究。在前一种情况下，单个分子聚集在晶体中，形成交叉的二聚体，Au···Au距离为3.60 ?，与弱亲金相互作用相容。在后一种情况下，观察到涉及膦化环的分子间Au···π相互作用，且Au···C的距离在约1〜3范围内。 3.32至3.44？，使[AuCl（C _5H_2P-2,4,6-Ph_3）]成为涉及杂芳烃的分子间Au··π相互作用的第一个结构表征实例。

著录项

来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |2013年第8期|共7页
作者
Stott J.; Bruhn C.; Siemeling U.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类 54;
关键词
Aurophilicity; Crystal structure; Gold; Gold-π interaction; Phosphinine;

机译：亲金性;晶体结构;金;金-π相互作用;磷脂;

相似文献

外文文献
中文文献
专利

1. Crystal structures of the gold(I) phosphinine complexes [AuCl(C _5H_2P-2,6-Me_2-4-Ph)] and [AuCl(C _5H_2P-2,4,6-Ph_3)] [J] . Stott J., Bruhn C., Siemeling U. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2013,第8期

机译：金（I）膦化合物[AuCl（C _5H_2P-2,6-Me_2-4-Ph）]和[AuCl（C _5H_2P-2,4,6-Ph_3）的晶体结构
2. SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] [J] . Assefa Z., Staples RJ., Fackler JP., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第1期

机译：1,3,5-三氮杂-7-磷酸金刚烷（TPA）的金（I）配合物的合成，结构和光谱性质-物种（TPA）AUCL和[[A）的分子间AU ... AU相互作用和光致发光的相关性（TPA-HCL）AUCL]
3. Gold Complexes [Ph3PCH2CH=CHCH2PPh3](2+)[AuCl4](2)(-) and [Ph3PCH2CH2COOH](+)[AuCl4](-): Synthesis and Structure [J] . Sharutin V. V., Sharutina O. K., Senchurin V. S. Russian Journal of Inorganic Chemistry . 2015,第8期

机译：金配合物[Ph3PCH2CH = CHCH2PPh3]（2 +）[AuCl4]（2）（-）和[Ph3PCH2CH2COOH]（+）[AuCl4]（-）：合成和结构
4. Quantum chemical study of AuCl_x(H_2O)_(4-x)~(3-x) (x=4,2) complexes [C] . Daria A. Pichugina, Alexander F. Shestakov, Nikolai E. Kuzmenko Symposium on High-Resolution Molecular Spectroscopy . 2004

机译：α（H_2O）_（4-X）〜（3-X）（X = 4,2）复合物的量子化学研究
5. Crystal structures of the Fanconi anemia proteins: Structure of the interstrand cross-linking repair protein Fanconi anemia protein I (FANCI); structure of the human FANCF C-terminal domain; reconstitution and crystallilzation of the sub-complexes in the Fanconi anemia core complex. [D] . Xu, Guozhou. 2009

机译：Fanconi贫血蛋白的晶体结构：链间交联修复蛋白Fanconi贫血蛋白I（FANCI）的结构；人FANCF C末端结构域的结构； Fanconi贫血核心复合物中亚复合物的重组和结晶。
6. Molecular Recognition of Metal Complexes by DNA: A Comparative Study of the Interactions of the Parent Complexes PtCl(TERPY)Cl and AuCl(TERPY)Cl2 with Double Stranded DNA [O] . Luigi Messori, Giordana Marcon, Alessio Innocenti, 2005

机译：DNA对金属配合物的分子识别：母体配合物PtCl（TERPY） Cl和AuCl（TERPY） Cl 2与双链DNA相互作用的比较研究
7. Different emission colors and photoexcited structures of AuCl(PPh3)2 in two polymorphic crystals [O] . M. Hoshino, H. Uekusa, S. Ishii, 2008

机译：两种多态性晶体中的AuCl（PPH3）2的不同发射颜色和运动膜结构

Crystal structures of the gold(I) phosphinine complexes [AuCl(C _5H_2P-2,6-Me_2-4-Ph)] and [AuCl(C _5H_2P-2,4,6-Ph_3)]

摘要

著录项

相似文献

相关主题

期刊订阅