On the mechanism of isospecific epoxide polymerization by salen cobalt(III)complexes: Evidence for solid-state catalysis

Hiroharu Ajiro; Kathryn L. Peretti; Emil B. Lobkovsky; Geoffrey W. Coates

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On the mechanism of isospecific epoxide polymerization by salen cobalt(III)complexes: Evidence for solid-state catalysis

机译：Salen钴（III）配合物进行同种异环氧化物聚合的机理：固态催化的证据

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Mechanistic studies have revealed that the isospecific poly-merization of epoxides by a discrete salen cobalt(III) catalystoccurs at the surface of the undissolved, crystalline complex.

机译：机理研究表明，离散的塞伦钴（III）催化剂在环氧化物的同种异型聚合作用发生在未溶解的晶体配合物表面。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2009年第41期|共3页
作者
Hiroharu Ajiro; Kathryn L. Peretti; Emil B. Lobkovsky; Geoffrey W. Coates;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
isospecific; epoxide; polymerization;

机译：等特异性;环氧;聚合;

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专利

1. On the mechanism of isospecific epoxide polymerization by salen cobalt(III)complexes: Evidence for solid-state catalysis [J] . Hiroharu Ajiro, Kathryn L. Peretti, Emil B. Lobkovsky, Dalton transactions: An international journal of inorganic chemistry . 2009,第41期

机译：Salen钴（III）配合物进行同种异环氧化物聚合的机理：固态催化的证据
2. Cobalt(III) Complexes of Various Salen-Type Ligand Bearing Four Quaternary
Ammonium Salts and Their Reactivity for CO₂/Epoxide Copolymerization [J] . Bo Eun Kim, Bun Yeoul Lee, Jobi Kodiyan Varghese, Bulletin of the Korean Chemical Society . 2010,第4期

机译：四种四元季铵盐的各种Salen型配体钴（III）配合物及其对CO _{2 /环氧共聚合的反应性}
3. Gas-Phase and Solution-Phase Polymerization of Epoxides by Cr(salen)Complexes:Evidence for a Dinuclear Cationic Mechanism [J] . Eva Schon, Xiangyang zhang, Zhiping Zhou Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第23期

机译：Cr（salen）络合物的气相气相和液相聚合反应：双核阳离子机理的证据
4. Synthesis of Macrocyclic Cobalt/Lanthanide Multinuclear Complexes for Copolymerization of An Epoxide with Carbon Dioxide and Study on Its Activity [C] . Hiroki Asaba, Takanori Iwasaki, Haruki Nagae 日本化学会春季年会講演予稿集 . 2018

机译：致癌钴/镧系元素多核复合物的合成与二氧化碳环氧化物共聚及其活性研究
5. Cobalt and chromium salen complexes catalyzed copolymerization of CO2 and epoxides: The scope of epoxides. [D] . Chung, Wan-Chun. 2015

机译：钴和铬塞伦络合物催化CO2和环氧化物的共聚：环氧化物的范围。
6. Influence of Co-Catalysts and Polymerization Conditions on Properties of Poly(anhydride-alt-epoxide)s from ROCOP Using Salen Complexes with Different Metals [O] . Matteo Proverbio, Nella Galotto Galotto, Simona Losio, 2019

机译：助催化剂和聚合条件对不同金属Salen配合物对ROCOP聚酸酐-环氧化合物性能的影响
7. Theoretical Study on Epoxide Ring-opening in CO2/Epoxide Copolymerization Catalyzed by Bifunctional Salen-Type Cobalt(III) Complexes: Influence of Stereoelectronic Factors [O] . Karol Dyduch, Aleksandra Roznowska, Monika Srebro-Hooper, 2021

机译：双官能盐酸钴（III）复合物催化催化环氧化环环开口的理论研究：立体电子因子的影响

On the mechanism of isospecific epoxide polymerization by salen cobalt(III)complexes: Evidence for solid-state catalysis

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