Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q=3,5-di-tert-butyl-benzoquinone

Sarkar B; Hubner R; Pattacini R; Hartenbach I

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q=3,5-di-tert-butyl-benzoquinone

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Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q=3,5-di-tert-butyl-benzoquinone

机译：在同分异构体复合物中组合两个非纯配体[Pt（pap）（m）Q（n）]（0）（pap =苯基偶氮吡啶，Q = 3,5-二叔丁基-苯醌

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Isomeric complexes of platinum, which contain two non-innocent ligands are reported. The built-in coordination asymmetry in the ligands makes it possible to separate two different positional isomers. Results from X-ray crystallography is used to invoke the popular structure oxidation state correlation in these complexes. The redox processes are discussed and interpreted with the help of UV-vis-NIR and EPR spectroelectrochemistry.

机译：据报道铂的异构体络合物包含两个非纯配体。配体中内置的配位不对称性使分离两个不同的位置异构体成为可能。 X射线晶体学的结果用于在这些配合物中调用流行的结构氧化态相关性。借助UV-vis-NIR和EPR光谱电化学技术对氧化还原过程进行了讨论和解释。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第24期|共3页
作者
Sarkar B; Hubner R; Pattacini R; Hartenbach I;
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正文语种 eng
中图分类化学;
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X-ray; UV-vis–NIR; EPR;

机译：X射线;紫外-近红外;EPR;

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1. Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q=3,5-di-tert-butyl-benzoquinone [J] . Sarkar B, Hubner R, Pattacini R, Dalton transactions: An international journal of inorganic chemistry . 2009,第24期

机译：在同分异构体复合物中组合两个非纯配体[Pt（pap）（m）Q（n）]（0）（pap =苯基偶氮吡啶，Q = 3,5-二叔丁基-苯醌
2. Sensitive Valence Structures of [(pap)(2)Ru(Q)](n) (n =+2,+1, 0,-1,-2)with Two Different Redox Noninnocent Ligands,Q=3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap=2-Phenylazopyridine [J] . Das D, Mondal TK, Mobin SM, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第20期

机译：[（pap）（2）Ru（Q）]（n）（n = + 2，+ 1，0，-1，-2）具有两个不同的氧化还原非无配体，Q = 3,5-Di的敏感价结构-叔丁基-N-芳基-1,2-苯醌单亚胺和pap = 2-苯基偶氮吡啶
3. Electrochemistry, Chemical Reactivity, and Time-Resolved Infrared Spectroscopy of Donor?Acceptor Systems [(Q~x)Pt(pap~y)] (Q = Substituted o?Quinone or o?Iminoquinone; pap = Phenylazopyridine) [J] . Naina Deibel, David Schweinfurth, Stephan Hohloch, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第2期

机译：供体受体系统的电化学，化学反应性和时间分辨红外光谱[[Q〜x] Pt（pap〜y）]（Q =取代的邻苯二醌或邻氨基苯醌; pap =苯基偶氮吡啶）
4. Artificial hydrogenases: Utilization of peptide and redox non-innocent ligands in FeFe and NiFe complexes [C] . Souvik Roy, Lu Gan, Arnab Dutta National Meeting Exhibition . 2013

机译：人工氢酶：利用肽和氧化还原非无辜配体在Fefe和NiFe复合物中的用途
5. Torn between two ligands: Structural, spectral, and reactivity studies of complexes of two redox non-innocent pincer ligands with trivalent vanadium. [D] . Curtis, Scott M. 2017

机译：在两个配体之间被撕裂：两个氧化还原非纯钳形配体与三价钒的配合物的结构，光谱和反应性研究。
6. ElectrochemistryChemical Reactivity and Time-ResolvedInfrared Spectroscopy of Donor–Acceptor Systems (Qx)Pt(papy) (Q = Substituted o-Quinone or o-Iminoquinone;pap = Phenylazopyridine) [O] . Naina Deibel, David Schweinfurth, Stephan Hohloch, -1

机译：电化学化学反应性和时间分辨供体-受体系统的红外光谱（Qx）Pt（papy）（Q =取代的邻醌或邻氨基醌；pap =苯基偶氮吡啶）
7. Electrochemistry, Chemical Reactivity, and Time-Resolved Infrared Spectroscopy of Donor–Acceptor Systems [(Q ^x )Pt(pap ^y )] (Q = Substituted o -Quinone or o -Iminoquinone; pap = Phenylazopyridine) [O] . Deibel N, Schweinfurth D, Hohloch S, 2014

机译：供体-受体系统的电化学，化学反应性和时间分辨红外光谱[（Q ^{x ）Pt（pap ^{y / sup>）]（Q =取代的 o -奎宁或 o -亚氨基醌； pap =苯基偶氮吡啶）}}

8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 84. Carbarorane Tungsten Platinum Complexes having a MU-CC6H3ME(2)-2,6 Ligand: Crystal Structures of (WPt(MU- CC6H3ME(2)-2,6))(CO)N-(Pet3)(MU- [R] . Devore, D. D., Howard, J. A., Jeffery, J. C., 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分84.具有mU-CC6H3mE（2）-2,6配体的碳硼烷钨铂配合物：（Wpt（mU-CC6H3mE（2）-2,6））（CO）N-（pet3）（mU-）的晶体结构

1. N─苯甲酰苯基羟胺／吡啶偶氮染料配体交换反应萃取分光光度法测定固体废物浸出液中的微量钒 [J] . 陈赋杏 ,李国刚 ,齐文启 . 干旱环境监测 . 1995,第3期

1. Using a drug consisting of at least one compound containing selenium and at least one pharmacologically acceptable acid in preparation for treatment of cervical cell changes, it is useful to have PAP III or PAP III and/or U levels. A Cin amp; o = a Cin 1. [P] . 外国专利： CL2013002353A1 . 2014-06-27

机译：在制备用于治疗宫颈细胞变化的制剂中使用由至少一种包含硒的化合物和至少一种药理学上可接受的酸组成的药物，具有PAP III或PAP III和/或U水平是有用的。 o =一分钱1。

2. PAPPER MED FOERBAETTRAD ABSORPTIONSFOERMAOGA SK absorbent PAPPER LAEMPLIGT laminating Før [P] . 外国专利： FI58961B . 1981-01-30

机译：FERBAETTRAD吸收纸SFOERMAOGA SK吸收纸PAPER LAEMPLIGT层压前

3. PAPPER MED FOERBAETTRAD ABSORPTIONSFOERMAOGA SK absorbent PAPPER LAEMPLIGT laminating Før [P] . 外国专利： FI58961C . 1981-05-11

机译：FERBAETTRAD吸收纸SFOERMAOGA SK吸收纸PAPER LAEMPLIGT层压前

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Combining two non-innocent ligands in isomeric complexes [Pt(pap)(m)Q(n)](0) (pap = phenylazopyridine, Q=3,5-di-tert-butyl-benzoquinone

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