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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Double carbonylation and beyond:systems at work and their organometallic models
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Double carbonylation and beyond:systems at work and their organometallic models

机译:双重羰基化及其他:正在运行的系统及其有机金属模型

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摘要

A quarter of a century after its(serendipitous)discovery,the catalytic sequential chaining of two carbon monoxides into an organic substrate(the so called double carbonylation reaction),is still not well understood.After a review of the most important experimental results,this Perspective proposes a critical survey of the main organometallic models and outlines some rather neglected tracks.Finally,the issue of the chaining of more than two carbon monoxides is also addressed.
机译:在发现(突然发生)的四分之一世纪之后,人们仍然不太了解将两个一氧化碳催化顺序地链接到有机底物中(所谓的双羰基化反应)。在回顾了最重要的实验结果之后,透视提出了对主要有机金属模型的批判性调查,并概述了一些相当被忽略的轨迹。最后,还解决了两种以上一氧化碳的链结问题。

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