Pyrrole-based metallo-macrocycles and cryptands

Paul D.Beer; Andrew G.Cheetham; Michael G.B.Drew; O.Danny Fox; Elizabeth J.Hayes; Toby D.Rolls

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Pyrrole-based metallo-macrocycles and cryptands

机译：基于吡咯的金属大环和穴状配体

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The synthesis of dithiocarbamate ligands based on a pyrrole framework is reported.These ligands self-assemble with zinc(II),nickel(II)and copper(II)to afford neutral,dinuclear metallomacrocycles and trinuclear melallocryptands.The assembled metallo compounds have been characterised by a range of techniques,including 'H NMR,UV-vis spectroscopy,elemental analysis,mass spectrometry and X-ray crystallography.Some preliminary anion binding studies have also been conducted,using electronic spectroscopy and electrochemistry.The nickel macrocycles showed some affinity for acetate,whereas the copper cryptand showed affinity for benzoate anions.The copper cryptand also exhibited a significant electrochemical response to a range of anions.

机译：报道了基于吡咯骨架的二硫代氨基甲酸酯配体的合成，这些配体与锌（II），镍（II）和铜（II）自组装得到中性，双核金属大环化合物和三核melallocryptands。通过1 H NMR，UV-vis光谱，元素分析，质谱和X射线晶体学等一系列技术。还使用电子光谱和电化学方法进行了一些初步的阴离子结合研究。镍大环化合物显示出对醋酸盐，而铜的穴状配体对苯甲酸酯阴离子具有亲和力。铜的穴状配体还对一系列阴离子表现出显着的电化学响应。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第4期|共9页
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Paul D.Beer; Andrew G.Cheetham; Michael G.B.Drew; O.Danny Fox; Elizabeth J.Hayes; Toby D.Rolls;
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1. Pyrrole-based metallo-macrocycles and cryptands [J] . Paul D.Beer, Andrew G.Cheetham, Michael G.B.Drew, Dalton transactions: An international journal of inorganic chemistry . 2003,第4期

机译：基于吡咯的金属大环和穴状配体
2. One-step electrochemically driven production of aza macrocycle-based pseudo-cryptand: An accessible route for creating of diverse cryptand-resembles compounds [J] . Shamsipur Mojtaba, Davarani Saied Saeed Hosseiny, Nematollahi Davood, Electrochimica Acta . 2019,第期

机译：基于AZA宏观的伪光线的一步电化学驱动的生产：用于创建多样化的Cryptand和类似化合物的可访问途径
3. Syntheses and Crystal Structures of (2.2.2-Cryptand)potassium Chloride and (2.2.2-Cryptand)ammonium Bromide_((0.75)) chloride_((0.25)) Hydrates [J] . A. N. Chekhlov Russian Journal of Inorganic Chemistry . 2009,第2期

机译：（2.2.2-Cryptand）氯化钾和（2.2.2-Cryptand）溴化铵_（（0.75））氯化物_（（0.25））水合物的合成和晶体结构
4. Pyrrole-based oligoamides for specific DNA recognition [C] . Sefan Asamitsu, Toshikazu Bando, Hiroshi Sugiyama 日本化学会春季年会講演予稿集 . 2018

机译：基于吡咯的寡聚酰胺，用于特定DNA识别
5. Synthesis, Reactivty, and Catalytic Applications of Iron Complexes Featuring Pyrrole-Based Pincer Ligands [D] . Thompson, C. Vance. 2020

机译：铁络合物的合成，重新活力和催化应用，其特征在于吡咯基钳子配体
6. Molecular recognition of planar and non-planar aromatic hydrocarbons through multipoint Ag–π bonding in a dinuclear metallo-macrocycle [O] . Kenichiro Omoto, Shohei Tashiro, Mitsuhiko Shionoya 2019

机译：通过双核金属-大环中的多点Ag-π键对平面和非平面芳烃的分子识别
7. Synthesis of rare-earth-metal-in-cryptand dications, Ln(2.2.2-cryptand)2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2 [O] . Daniel N. Huh, Christopher M. Kotyk, Milan Gembicky, 2017

机译：稀土金属封氏碱基的合成LN（2.2.2-碱基） 2+，来自SM2 +，EU2 +和YB2 +甲硅烷基茂金属（C5H4SIME3）2LN（THF）2

Pyrrole-based metallo-macrocycles and cryptands

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