The reaction of tin(iv) iodide with phosphines: Formation of new halotin anions

Apostolico L.; Kociok-K?hn G.; Molloy K.C.; Blackman C.S.; Carmalt C.J.; Parkin I.P.

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The reaction of tin(iv) iodide with phosphines: Formation of new halotin anions

机译：碘化锡（iv）与膦的反应：形成新的卤代阴离子

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The reaction of SnI_4 with each of a primary, secondary and tertiary phosphine has been investigated and in none of the cases are simple adducts formed. With Cy_3P, [Cy_3PI]~+ salts of both [SnI_3]~- (1) and [SnI_5]~- (2) are isolated arising from reactions involving both reduction at tin and halogen transfer. With the secondary and primary amines Ph_2PH and CyPH_ 2, respectively, additional HI elimination reactions occur and the salts [Ph_2PH_2]~+_ 6[Sn_ 3I_(12)]~(6-) (3), [Ph_2PH_ 2]~+_ 2[SnI_6]~(2-) (4) and [CyPH_3]~+ _2[SnI_4]~(2-) (5) have been isolated. Compounds 1-5 have been characterised crystallographically.

机译：已经研究了SnI_4与伯，仲和叔膦各自的反应，在任何情况下都没有形成简单的加合物。对于Cy_3P，分离了[SnI_3]〜-（1）和[SnI_5]〜-（2）的[Cy_3PI]〜+盐，其反应涉及锡转移和卤素转移的还原。分别与仲胺和伯胺Ph_2PH和CyPH_2发生额外的HI消除反应，盐[Ph_2PH_2]〜+ _ 6 [Sn_ 3I_（12）]〜（6-）（3），[Ph_2PH_2]〜+ _ 2 [SnI_6]〜（2-）（4）和[CyPH_3]〜+ _2 [SnI_4]〜（2-）（5）已被隔离。化合物1-5已经通过结晶学表征。

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《Dalton transactions: An international journal of inorganic chemistry》 |2009年第47期|共9页
作者
Apostolico L.; Kociok-K?hn G.; Molloy K.C.; Blackman C.S.; Carmalt C.J.; Parkin I.P.;
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正文语种 eng
中图分类化学;无机化学;
关键词
phosphines; Formation; halotin;

机译：膦;形成;盐蛋白;

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1. The reaction of tin(IV) iodide with phosphines: formation of new halotin anions [J] . Apostolico L, Kociok-Kohn G, Molloy KC, Dalton transactions: An international journal of inorganic chemistry . 2010,第47期

机译：碘化锡（IV）与膦的反应：形成新的卤代阴离子
2. The reaction of tin(iv) iodide with phosphines: Formation of new halotin anions [J] . Apostolico L., Kociok-K?hn G., Molloy K.C., Dalton transactions: An international journal of inorganic chemistry . 2009,第47期

机译：碘化锡（iv）与膦的反应：形成新的卤代阴离子
3. The reaction of tin(IV) iodide with phosphines: formation of new halotin anions [J] . Apostolico L, Kociok-Kohn G, Molloy KC, Dalton transactions: An international journal of inorganic chemistry . 2009,第47期

机译：碘化锡（IV）与膦的反应：形成新的卤代阴离子
4. Reaction of 2-propynyl Mesylates and Aldehydes with Tin(IV)Iodide and Tetrabutylammonium Iodide [C] . Yoshiro Masuyama, Rvouichi Yamazuki, Yasuhiko Kurusu Symposium on Organometallic Chemistry . 2003

机译：用锡（IV）碘化锡和四丁基碘化物的2-丙炔基甲磺酸和醛的反应
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机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
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The reaction of tin(iv) iodide with phosphines: Formation of new halotin anions

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