Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

OLeary P; van Walree CA; Mehendale NC; Sumerel J; Morse DE; Kaska WC; van Koten G; Gebbink RJMK

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

【24h】

Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

机译：酶固定化有机金属物种：使用脱海绵轴向长丝对NCN和PCP钳金属物种进行生物硅化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Silicatein protein filaments isolated from marine demosponges have been used to influence the condensation of siloxanes bearing organometallic pincer complexes. The siliceous material is formed under remarkably mild conditions and the organometallic pincer becomes an intrinsic part of the silica. The immobilisation of a metal pincer, which acts as a sensor and initial results on the immobilisation of a pre-catalytic pincer species are reported.

机译：从海洋海绵中分离出的硅酸盐蛋白丝已用于影响带有有机金属钳形配合物的硅氧烷的缩合。硅质材料是在非常温和的条件下形成的，有机金属钳成为二氧化硅的固有部分。报道了金属钳的固定化，该金属钳用作传感器，并且报道了固定前催化钳物种的初步结果。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2009年第22期|共3页
作者
OLeary P; van Walree CA; Mehendale NC; Sumerel J; Morse DE; Kaska WC; van Koten G; Gebbink RJMK;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
MESOPOROUS SILICA; COMPLEXES; CATALYSTS; PALLADIUM(II); SWITCHES; ALPHA;

机译：介孔二氧化硅;复合物;催化剂;钯（II）;开关;阿尔法;

相似文献

外文文献
中文文献
专利

1. Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments [J] . OLeary P, van Walree CA, Mehendale NC, Dalton transactions: An international journal of inorganic chemistry . 2009,第22期

机译：酶固定化有机金属物种：使用脱海绵轴向长丝对NCN和PCP钳金属物种进行生物硅化
2. Fractal-related assembly of the axial filament in the demosponge Suberites domuncula: relevance to biomineralization and the formation of biogenic silica. [J] . Muller WE, Boreiko A, Schlossmacher U, Biomaterials . 2007,第30期

机译：脱节海绵Suberites domuncula中轴向细丝的分形相关组装：与生物矿化和生物硅的形成有关。
3. Analysis of the axial filament in spicules of the demosponge Geodia cydonium: different silicatein composition in microscleres (asters) and megascleres (oxeas and triaenes) [J] . Muller WE, Schlossmacher U, Eckert C, European Journal of Cell Biology: Journal of Deutsche Gesellschaft fur Elektronenmikroskopie: Journal of Deutsche Gesellschaft fur Zellbiologie . 2007,第8期

机译：脱毛大孢子藻的针状体中的轴向丝的分析：微菌（紫苑）和大菌（草和三叶草）中不同的硅酸盐成分
4. Iron-Catalyzed Cross-Coupling of Alkyl/Aryl Halides with Organometallic species(Abstracts) [C] . Michael Huwe, Robin B.Bedford European Symposium on Organic Chemistry . 2007

机译：烷基/芳基卤化物与有机金属物质（摘要）的铁催化交叉偶联
5. Synthesis and reaction chemistry of homonuclear metal-metal bonded group 12 (zinc, cadmium and mercury) and group 13 (gallium and indium) organometallic compounds ArMMAr (Ar = terphenyl ligands) and related species. [D] . Zhu, Zhongliang. 2009

机译：同核金属-金属键合的12族（锌，镉和汞）和13族（镓和铟）有机金属化合物ArMMAr（Ar =三联苯配体）及相关物质的合成和反应化学。
6. Extraction/Preconcentration Procedures for Determination of Metal and Organometallic Species in Environmental, Biological, and Food Samples [O] . Marcela Zanetti Corazza, Vanessa Egea dos Anjos, Seyyed E. Moradi 1952

机译：测定环境，生物和食品样品中金属和有机金属物种的提取/预浓缩程序
7. Where organometallics and dendrimers merge: the incorporation of organometallic species into dendritic molecules [O] . Preston A. Chase, Robertus J.M. Klein Gebbink, Gerard van Koten 2004

机译：有机金属和树枝状大分子合并：将有机金属物种掺入树枝状分子中

Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments

摘要

著录项

相似文献

相关主题

期刊订阅